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Sodium polyacrylate (ACR, ASAP, or PAAS), [1]: 233 also known as waterlock, is a sodium salt of polyacrylic acid with the chemical formula [−CH 2 −CH(CO 2 Na)−] n and has broad applications in consumer products.
Polyacrylic acid is a weak anionic polyelectrolyte, whose degree of ionisation is dependent on solution pH. In its non-ionised form at low pHs, PAA may associate with various non-ionic polymers (such as polyethylene oxide, poly-N-vinyl pyrrolidone, polyacrylamide, and some cellulose ethers) and form hydrogen-bonded interpolymer complexes. [17]
Superabsorbent polymers are now commonly made from the polymerization of acrylic acid blended with sodium hydroxide in the presence of an initiator to form a poly-acrylic acid sodium salt (sometimes referred to as sodium polyacrylate). This polymer is the most common type of SAP made in the world today.
Acrylates (IUPAC: prop-2-enoates) are the salts, esters, and conjugate bases of acrylic acid.The acrylate ion is the anion CH 2 =CHCO − 2.Often, acrylate refers to esters of acrylic acid, the most common member being methyl acrylate.
The reaction results in a polymer which is also soluble in the chosen solvent. Heat released by the reaction is absorbed by the solvent, reducing the reaction rate. Moreover, the viscosity of the reaction mixture is reduced, preventing autoacceleration at high monomer concentrations. A decrease in viscosity of the reaction mixture by dilution ...
Acrylic acid undergoes the typical reactions of a carboxylic acid. When reacted with an alcohol, it forms the corresponding ester. The esters and salts of acrylic acid are collectively known as acrylates (or propenoates). The most common alkyl esters of acrylic acid are methyl, butyl, ethyl, and 2-ethylhexyl acrylate.
Structure of a polyacrylate polymer. An acrylate polymer (also known as acrylic or polyacrylate) is any of a group of polymers prepared from acrylate monomers. These plastics are noted for their transparency, resistance to breakage, and elasticity. Acrylate polymer is commonly used in cosmetics, such as nail polish, as an adhesive. [1]
Isomers of the repeating unit in polyaspartic acid.. Polycarboxylates are used as builders in detergents. [2] Their high chelating power, even at low concentrations, reduces deposits on the laundry and inhibits the crystal growth of calcite.