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Vinyl chloride is an organochloride with the formula H 2 C=CHCl. It is also called vinyl chloride monomer (VCM) or chloroethene. It is an important industrial chemical chiefly used to produce the polymer polyvinyl chloride (PVC). Vinyl chloride is a colourless flammable gas that has a sweet odor and is carcinogenic.
In the early 1970s, the carcinogenicity of vinyl chloride (usually called vinyl chloride monomer or VCM) was linked to cancers in workers in the polyvinyl chloride industry. Specifically workers in polymerization section of a B.F. Goodrich plant near Louisville, Kentucky , were diagnosed with liver angiosarcoma also known as hemangiosarcoma , a ...
In polymer chemistry, polymerisation inhibitors (US: polymerization inhibitors) are chemical compounds added to monomers to prevent their self-polymerisation. Unsaturated monomers such as acrylates, vinyl chloride, butadiene and styrene require inhibitors for both processing and safe transport and storage.
If the polymer is to be used for the disinfection of water, then it should be insoluble in water to prevent toxicity issues (as is the case with some current small molecule antimicrobial agents). The polymer should not decompose during use, or emit toxic residues. The polymer should not be toxic or irritating to those during handling.
Vinyl polymers are subject of several structural variations, which greatly expands the range of polymers and their applications. With the exception of polyethylene, vinyl polymers can arise from head-to-tail linking of monomers, head-to-head combined with tail-to-tail, or a mixture of those two patterns. Additionally the substituted carbon center in such polymers is stereogenic (a "chiral center")
In some countries other than the United States, vinyon fibers are referred to as polyvinyl chloride fibers. It can bind non-woven fibers and fabrics. It was invented in 1939. It has the same health problems associated with chlorinated polymers. In the past, Vinyon was used a substitute for plant-based filters in tea bags.
Vinyl chloride is produced by dehydrochlorination of 1,2-dichloroethane. [1] Due to their high utility, many approaches to vinyl halides have been developed, such as: reactions of vinyl organometallic species with halogens; Takai olefination; Stork-Zhao olefination with, e.g., (Chloromethylene)triphenylphosphorane - a modification of the Wittig ...
Polyvinylidene chloride is applied as a water-based coating to films made of other plastics, such as biaxially-oriented polypropylene (BOPP) and polyethylene terephthalate (PET). This coating increases the barrier properties of the film, reducing the permeability of the film to oxygen and flavours and thus extending the shelf life of the food ...