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Carboxylate ion Acrylate ion. In organic chemistry, a carboxylate is the conjugate base of a carboxylic acid, RCOO − (or RCO − 2). It is an anion, an ion with negative charge. Carboxylate salts are salts that have the general formula M(RCOO) n, where M is a metal and n is 1, 2,....
Alternately, it can be named as a "carboxy" or "carboxylic acid" substituent on another parent structure, such as 2-carboxyfuran. The carboxylate anion (R−COO − or R−CO − 2) of a carboxylic acid is usually named with the suffix -ate, in keeping with the general pattern of -ic acid and -ate for a conjugate acid and its conjugate base ...
For example, a carboxylic acid is defined as a carbonyl group (C=O) directly attached to a hydroxyl group (OH): O=C–OH. A vinylogous carboxylic acid has a vinyl unit (−HC=CH−, vinylene) between the two groups that define the acid: O=C–C=C–OH. The usual resonance of a
The name of the carboxylate anion (R−C(=O)O −) is derived from that of the parent acid by replacing the "–oic acid" ending with "–oate" or "carboxylate." For example, NaC 6 H 5 CO 2, the sodium salt of benzoic acid (C 6 H 5 COOH), is called sodium benzoate. Where an acid has both a systematic and a common name (like CH 3 COOH, for ...
In chemistry, an acyl group is a moiety derived by the removal of one or more hydroxyl groups from an oxoacid, [1] including inorganic acids. It contains a double-bonded oxygen atom and an organyl group ( R−C=O ) or hydrogen in the case of formyl group ( H−C=O ).
An oxocarbon anion C x O n− y can be seen as the result of removing all protons from a corresponding acid C x H n O y. Carbonate CO 2− 3, for example, can be seen as the anion of carbonic acid H 2 CO 3. Sometimes the "acid" is actually an alcohol or other species; this is the case, for example, of acetylenediolate C 2 O 2− 2 that would ...
Structure of hydrated nickel acetate. Transition metal carboxylate complexes are coordination complexes with carboxylate (RCO 2 −) ligands. Reflecting the diversity of carboxylic acids, the inventory of metal carboxylates is large. Many are useful commercially, and many have attracted intense scholarly scrutiny.
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