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In 1897, an unfermentable product obtained by treatment of fructose with bases, in particular lead(II) hydroxide, was given the name glutose, a portmanteau of glucose and fructose, and was claimed to be a 3-ketohexose. [12] [13] However, subsequent studies showed that the substance was a mixture of various other compounds. [13] [14]
A open-chain form of glucose makes up less than 0.02% of the glucose molecules in an aqueous solution at equilibrium. [57] The rest is one of two cyclic hemiacetal forms. In its open-chain form, the glucose molecule has an open (as opposed to cyclic) unbranched backbone of six carbon atoms, where C-1 is part of an aldehyde group H(C=O)−.
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For many monosaccharides (including glucose), the cyclic forms predominate, in the solid state and in solutions, and therefore the same name commonly is used for the open- and closed-chain isomers. Thus, for example, the term "glucose" may signify glucofuranose, glucopyranose, the open-chain form, or a mixture of the three.
The carbons of the chain are conventionally numbered from 1 to n, starting from the end which is closest to the carbonyl. If the carbonyl is at the very beginning of the chain (carbon 1), the monosaccharide is said to be an aldose, otherwise it is a ketose. These names can be combined with the chain length prefix, as in aldohexose or ...
For example, in living organisms, the open-chain isomer of glucose usually exists only transiently, in small amounts; D-glucose is the usual isomer; and L-glucose is rare. Straight-chain molecules are often not literally straight, in the sense that their bond angles are often not 180°, but the name reflects that they are schematically straight ...
The ends of levan also tend to contain a glucosyl residue. [4] Branched levan tends to be more stable than linear polysaccharides. [5] However, the amount of branching and length of polymerization tends to vary among different species. [4] The shortest levan is 6-kestose, a chain of two fructose molecules and a terminal glucose molecule.
High fructose corn syrup (HFCS) [1] – made from corn starch, containing from 55% fructose [3] to 90% fructose. High maltose corn syrup – mainly maltose, not as sweet as high fructose corn syrup; Honey [1] – consists of fructose and glucose; Inositol [2] – naturally occurring sugar alcohol. Commercial products are purified from corn.