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The grand canonical partition function applies to a grand canonical ensemble, in which the system can exchange both heat and particles with the environment, at fixed temperature, volume, and chemical potential. Other types of partition functions can be defined for different circumstances; see partition function (mathematics) for
The partition function or configuration integral, as used in probability theory, information theory and dynamical systems, is a generalization of the definition of a partition function in statistical mechanics. It is a special case of a normalizing constant in probability theory, for the Boltzmann distribution.
A partition in which no part occurs more than once is called strict, or is said to be a partition into distinct parts. The function q(n) gives the number of these strict partitions of the given sum n. For example, q(3) = 2 because the partitions 3 and 1 + 2 are strict, while the third partition 1 + 1 + 1 of 3 has repeated parts.
The only partition of zero is the empty sum, having no parts. The order-dependent composition 1 + 3 is the same partition as 3 + 1, and the two distinct compositions 1 + 2 + 1 and 1 + 1 + 2 represent the same partition as 2 + 1 + 1. An individual summand in a partition is called a part. The number of partitions of n is given by the partition ...
In statistical mechanics, the translational partition function, is that part of the partition function resulting from the movement (translation) of the center of mass. For a single atom or molecule in a low pressure gas, neglecting the interactions of molecules , the canonical ensemble q T {\displaystyle q_{T}} can be approximated by: [ 1 ]
Generally, a partition is a division of a whole into non-overlapping parts. Among the kinds of partitions considered in mathematics are partition of a set or an ordered partition of a set,
The initial idea is usually attributed to the work of Hardy with Srinivasa Ramanujan a few years earlier, in 1916 and 1917, on the asymptotics of the partition function.It was taken up by many other researchers, including Harold Davenport and I. M. Vinogradov, who modified the formulation slightly (moving from complex analysis to exponential sums), without changing the broad lines.
Vibrational partition function, partition function for the vibrational modes of a molecule; Partition function (quantum field theory), partition function for quantum path integrals; Partition function (mathematics), generalization of the statistical mechanics concept; Partition function (number theory), the number of possible partitions of an ...