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Polyvinyl alcohol (PVOH, PVA, or PVAl) is a water-soluble synthetic polymer. It has the idealized formula [CH 2 CH(OH)] n . It is used in papermaking , textile warp sizing , as a thickener and emulsion stabilizer in polyvinyl acetate (PVAc) adhesive formulations, in a variety of coatings, and 3D printing .
Vinyl alcohol, also called ethenol (IUPAC name; not ethanol) or ethylenol, is the simplest enol. With the formula C H 2 CH O H , it is a labile compound that converts to acetaldehyde immediately upon isolation near room temperature. [ 1 ]
Vinyl polymers are subject of several structural variations, which greatly expands the range of polymers and their applications. With the exception of polyethylene, vinyl polymers can arise from head-to-tail linking of monomers, head-to-head combined with tail-to-tail, or a mixture of those two patterns. Additionally the substituted carbon center in such polymers is stereogenic (a "chiral center")
For instance, polyvinyl alcohol is (CH 2 CHOH) n with n hydroxyl groups where n can be in the thousands. Cellulose is a polymer with many hydroxyl groups, but it is not referred to as a polyol. Polyols from recycled or renewable sources
The degree of polymerization of polyvinyl acetate is typically 100 to 5000, while its ester groups are sensitive to base hydrolysis and slowly convert PVAc into polyvinyl alcohol and acetic acid. The glass transition temperature of polyvinyl acetate is between 30 and 45 °C depending on the molecular weight.
Chessboard made from polyvinyl chloride. Vinyl is one of the alkenyl functional groups. On a carbon skeleton, sp 2-hybridized carbons or positions are often called vinylic. Allyls, acrylates and styrenics contain vinyl groups. (A styrenic crosslinker with two vinyl groups is called divinyl benzene.)
Vinyl acetate is the acetate ester of vinyl alcohol. Since vinyl alcohol is highly unstable (with respect to acetaldehyde), the preparation of vinyl acetate is more complex than the synthesis of other acetate esters. The major industrial route involves the reaction of ethylene and acetic acid with oxygen in the presence of a palladium catalyst. [6]
Polyvinyl chloride (PVC), a particular vinyl polymer; Vinyl cation, a type of carbocation; Vinyl group, a broad class of organic molecules in chemistry; Vinyl polymer, a group of polymers derived from vinyl monomers