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The Stark effect is the shifting and splitting of spectral lines of atoms and molecules due to the presence of an external electric field. It is the electric-field analogue of the Zeeman effect , where a spectral line is split into several components due to the presence of the magnetic field .
In spectroscopy, the Autler–Townes effect (also known as AC Stark effect), is a dynamical Stark effect corresponding to the case when an oscillating electric field (e.g., that of a laser) is tuned in resonance (or close) to the transition frequency of a given spectral line, and resulting in a change of the shape of the absorption/emission spectra of that spectral line.
The splitting of the energy levels of an atom or molecule when subjected to an external electric field is known as the Stark effect. For the hydrogen atom, the perturbation Hamiltonian is H ^ s = − | e | E z {\displaystyle {\hat {H}}_{s}=-|e|Ez} if the electric field is chosen along the z -direction.
The Stark effect – splitting because of an external electric field. In physical chemistry: The Jahn–Teller effect – splitting of electronic levels in a molecule because breaking the symmetry lowers the energy when the degenerate orbitals are partially filled. Resonance (chemistry) leads to creation of delocalized electron states.
Linear Stark broadening occurs via the linear Stark effect, which results from the interaction of an emitter with an electric field of a charged particle at a distance , causing a shift in energy that is linear in the field strength. (/)
Stark spectroscopy (sometimes known as electroabsorption/emission spectroscopy) is a form of spectroscopy based on the Stark effect.In brief, this technique makes use of the Stark effect (or electrochromism) either to reveal information about the physiochemical or physical properties of a sample using a well-characterized electric field or to reveal information about an electric field using a ...
The quantum-confined Stark effect (QCSE) describes the effect of an external electric field upon the light absorption spectrum or emission spectrum of a quantum well (QW). In the absence of an external electric field, electrons and holes within the quantum well may only occupy states within a discrete set of energy subbands. Only a discrete set ...
It is analogous to the Stark effect, the splitting of a spectral line into several components in the presence of an electric field. Also, similar to the Stark effect, transitions between different components have, in general, different intensities, with some being entirely forbidden (in the dipole approximation), as governed by the selection rules.