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Paul Sabatier (1854-1941) winner of the Nobel Prize in Chemistry in 1912 and discoverer of the reaction in 1897. The Sabatier reaction or Sabatier process produces methane and water from a reaction of hydrogen with carbon dioxide at elevated temperatures (optimally 300–400 °C) and pressures (perhaps 3 MPa [1]) in the presence of a nickel catalyst.
Temperatures in excess of 1200 °C are required to break the bonds of methane to produce hydrogen gas and solid carbon. [36] However, through the use of a suitable catalyst the reaction temperature can be reduced to between 550 and 900 °C depending on the chosen catalyst.
Methane (CH 4) in the Earth's atmosphere is a powerful greenhouse gas with a global warming potential (GWP) 84 times greater than CO 2 over a 20-year time frame. [22] [23] Methane is not as persistent as CO 2, and tails off to about 28 times greater than CO 2 over a 100-year time frame. [10]
The reaction takes place in a single chamber where the methane is partially oxidized. The reaction is exothermic. When the ATR uses carbon dioxide, the H 2:CO ratio produced is 1:1; when the ATR uses steam, the H 2:CO ratio produced is 2.5:1. The outlet temperature of the syngas is between 950–1100 °C and outlet pressure can be as high as ...
High temperature hydrogen attack (HTHA), also called hot hydrogen attack or methane reaction, is a problem which concerns steels operating at elevated temperatures (typically above 400 °C (752 °F)) in hydrogen-rich atmospheres, such as refineries, petrochemical and other chemical facilities and, possibly, high pressure steam boilers.
Further reactions occur when the formed carbon monoxide and residual water from the organic material react to form methane and excess carbon dioxide (4CO + 2H 2 O → CH 4 + 3CO 2). This third reaction occurs more abundantly in reactors that increase the residence time of the reactive gases and organic materials, as well as heat and pressure.
Methanation is the conversion of carbon monoxide and carbon dioxide (CO x) to methane (CH 4) through hydrogenation. The methanation reactions of CO x were first discovered by Sabatier and Senderens in 1902. [1] CO x methanation has many practical applications.
Table data obtained from CRC Handbook of Chemistry and Physics 44th ed. Annotation "(s)" indicates equilibrium temperature of vapor over solid. Otherwise temperature is equilibrium of vapor over liquid. Note that these are all negative temperature values. Methane vapor pressure vs. temperature.