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1-Chlorobutane is an alkyl halide with the chemical formula CH 3 (CH 2) 3 Cl. It is a colorless, flammable liquid. It is a colorless, flammable liquid. Preparation and reactions
tert-Butyl chloride is the organochloride with the formula (CH 3) 3 CCl. It is a colorless, flammable liquid. It is sparingly soluble in water, with a tendency to undergo hydrolysis to the corresponding tert-butyl alcohol. It is produced industrially as a precursor to other organic compounds. [1]
tertiary (5) > secondary (3.8) > primary (1). Thus any single chlorination step slightly favors substitution at the carbon already most substituted. The rates are generally constant across reactions and predict product distributions with relatively high accuracy. [3] [4] For example, 2-methyl butane ((CH 3) 2 CHCH 2 CH 3) exhibits the following ...
This page contains tables of azeotrope data for various binary and ternary mixtures of solvents. The data include the composition of a mixture by weight (in binary azeotropes, when only one fraction is given, it is the fraction of the second component), the boiling point (b.p.) of a component, the boiling point of a mixture, and the specific gravity of the mixture.
In the similar substitution of 1-chloro-3-methyl-2-butene, the secondary 2-methyl-3-buten-2-ol is produced in a yield of 85%, while that for the primary 3-methyl-2-buten-1-ol is 15%. Allylic shifts occur because the transition state is an allyl intermediate.
1-chloro-2-methylbenzene 1-chloro-3-methylbenzene 1-chloro-4-methylbenzene Molecular formula: C 7 H 7 Cl (C 6 H 4 ClCH 3) Molar mass: 126.586 g/mol Appearance colorless liquid CAS number [95-49-8] [108-41-8] [106-43-4] Properties Density and phase: 1.073 g/ml, liquid 1.072 g/ml, liquid 1.069 g/ml, liquid Solubility in water: practically ...
1,1,1,3,3,3-Hexachloropropane is a compound of chlorine, hydrogen, and carbon, with chemical formula C 3 Cl 6 H 2, specifically Cl 3 C−CH 2 −CCl 3. Its molecule can be described as that of propane with chlorine atoms substituted for the six hydrogen atoms on the extremal carbons.
The photochlorination of hydrocarbon is unselective, although the reactivity of the C-H bonds is tertiary>secondary>primary. At 30 °C the relative reaction rates of primary, secondary and tertiary hydrogen atoms are in a relative ratio of approximately 1 to 3.25 to 4.43. The C-C bonds remain unaffected. [9] [10]