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Polyvinyl alcohol (PVOH, PVA, or PVAl) is a water-soluble synthetic polymer. It has the idealized formula [CH 2 CH(OH)] n . It is used in papermaking , textile warp sizing , as a thickener and emulsion stabilizer in polyvinyl acetate (PVAc) adhesive formulations, in a variety of coatings, and 3D printing .
The degree of polymerization of polyvinyl acetate is typically 100 to 5000, while its ester groups are sensitive to base hydrolysis and slowly convert PVAc into polyvinyl alcohol and acetic acid. The glass transition temperature of polyvinyl acetate is between 30 and 45 °C depending on the molecular weight.
In polymer chemistry, vinyl polymers are a group of polymers derived from substituted vinyl (H 2 C=CHR) monomers. Their backbone is an extended alkane chain [−CH 2 −CHR−] . [ 1 ] In popular usage, "vinyl" refers only to polyvinyl chloride (PVC).
Vinylon, also known as Vinalon (more common in Korean sources), is a synthetic fiber produced from reaction between polyvinyl alcohol (PVA) fiber and formaldehyde. Chemically it is polyvinyl formal (PVF). Vinylon was first developed in Japan in 1939 by Ri Sung-gi, Ichiro Sakurada, and H. Kawakami. [1]
Vinyl alcohol, also called ethenol (IUPAC name; not ethanol) or ethylenol, is the simplest enol. With the formula C H 2 CH O H , it is a labile compound that converts to acetaldehyde immediately upon isolation near room temperature. [ 1 ]
Flubber polymer with green food coloring added. The polymer is normally colorless. Flubber (named from the film The Absent-Minded Professor), Glorp, Glurch, or Slime is a rubbery polymer formed by cross-linking of polyvinyl alcohol (PVA) with a borate compound. Slime can be made by combining polyvinyl-acetate-based adhesives with borax. [1]
Polyethylene glycol–polyvinyl alcohol (PEG-PVA) brand name Kollicoat IR is a multifunctional excipient [1] used as a pill binder as well as a wet binder. A typical formulation is composed of 25% polyethylene glycol (PEG) and 75% polyvinyl alcohol (PVA); where the vinyl alcohol moieties are grafted on a polyethylene glycol backbone.
Polyvinyl nitrate is a long carbon chain (polymer) with nitrate groups () bonded randomly along the chain. PVN is a white, fibrous solid, and is soluble in polar organic solvents such as acetone . PVN can be prepared by nitrating polyvinyl alcohol with an excess of nitric acid .