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Scandium(III) oxide or scandia is a inorganic compound with formula Sc 2 O 3.It is one of several oxides of rare earth elements with a high melting point.It is used in the preparation of other scandium compounds as well as in high-temperature systems (for its resistance to heat and thermal shock), electronic ceramics, and glass composition (as a helper material).
Scandium concentrates in the liver and is a threat to it; some of its compounds are possibly carcinogenic, even though in general scandium is not toxic. [80] Scandium is known to have reached the food chain, but in trace amounts only; a typical human takes in less than 0.1 micrograms per day. [80]
Scandium has been proposed for use in solid oxide fuel cells (SOFCs) as a dopant in the electrolyte material, typically zirconia (ZrO₂). [72] Scandium oxide (Sc₂O₃) is one of several possible additives to enhance the ionic conductivity of the zirconia, improving the overall thermal stability, performance and efficiency of the fuel cell. [73]
In all four halides, the scandium is 6-coordinated. They can be prepared by reacting scandium oxide or scandium hydroxide with the corresponding acid: [3] Sc(OH) 3 + 3 HX → ScX 3 + 3 H 2 O. The halides are Lewis acids; for example, ScF 3 dissolves in a solution containing excess fluoride ion to form [ScF 6] 3−. The coordination number 6 is ...
Lanthanum oxide is a white solid that can be prepared by direct reaction of its constituent elements. Due to the large size of the La 3+ ion, La 2 O 3 adopts a hexagonal 7-coordinate structure that changes to the 6-coordinate structure of scandium oxide (Sc 2 O 3) and yttrium oxide (Y 2 O 3) at high temperature.
Kangite is an exceedingly rare scandium mineral, a natural form of impure scandium oxide (Sc 2 O 3), with the formula (Sc,Ti,Al,Zr,Mg,Ca, ) 2 O 3. It crystallizes in the cubic crystal system diploidal class. [1] In terms of chemistry it scandium-analogue of tistarite. Both kangite and tistarite were discovered in the Allende meteorite. [2] [1 ...
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Scandium is present in many ixiolite sample with percentages up to 4.0 percent Sc 2 O 3, but usually less than one percent scandium oxide. High scandium ixiolites, containing from 4 to 19% scandium oxide are typically also rich in tin and titanium.