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This is illustrated in the vapor pressure chart (see right) that shows graphs of the vapor pressures versus temperatures for a variety of liquids. [7] At the normal boiling point of a liquid, the vapor pressure is equal to the standard atmospheric pressure defined as 1 atmosphere, [ 1 ] 760 Torr, 101.325 kPa, or 14.69595 psi.
Values are given in terms of temperature necessary to reach the specified pressure. Valid results within the quoted ranges from most equations are included in the table for comparison. A conversion factor is included into the original first coefficients of the equations to provide the pressure in pascals (CR2: 5.006, SMI: -0.875).
where P 1, P 2 are the vapor pressures at temperatures T 1, T 2 respectively, ΔH vap is the enthalpy of vaporization, and R is the universal gas constant. The rate of evaporation in an open system is related to the vapor pressure found in a closed system. If a liquid is heated, when the vapor pressure reaches the ambient pressure the liquid ...
The boiling point of water is the temperature at which the saturated vapor pressure equals the ambient pressure. Water supercooled below its normal freezing point has a higher vapor pressure than that of ice at the same temperature and is, thus, unstable. Calculations of the (saturation) vapor pressure of water are commonly used in meteorology.
The vapor pressure chart to the right has graphs of the vapor pressures versus temperatures for a variety of liquids. [10] As can be seen in the chart, the liquids with the highest vapor pressures have the lowest normal boiling points. For example, at any given temperature, methyl chloride has the highest vapor pressure of any of the liquids in ...
A log-lin vapor pressure chart for various liquids. Vapor pressure is a measurement of how readily a condensed phase forms a vapor at a given temperature. A substance enclosed in a sealed vessel initially at vacuum (no air inside) will quickly fill any empty space with vapor.
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Group → 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18; ↓ Period 1: H 2 20.271 K (−252.879 °C) He 4.222 K (−268.928 °C) 2: Li 1603 K (1330 °C) Be 2742 K ...