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In aqueous solutions, redox potential is a measure of the tendency of the solution to either gain or lose electrons in a reaction. A solution with a higher (more positive) reduction potential than some other molecule will have a tendency to gain electrons from this molecule (i.e. to be reduced by oxidizing this other molecule) and a solution with a lower (more negative) reduction potential ...
In solid-state physics, the valence band and conduction band are the bands closest to the Fermi level, and thus determine the electrical conductivity of the solid. In nonmetals, the valence band is the highest range of electron energies in which electrons are normally present at absolute zero temperature, while the conduction band is the lowest range of vacant electronic states.
At high concentrations, a deviation from the nearest-neighbour model is observed, and variable-range hopping is used instead to describe transport. Variable range hopping can be used to describe disordered systems such as molecularly-doped polymers, low molecular weight glasses and conjugated polymers. [ 3 ]
The 20 °C value is only an approximation when used at other temperatures. For example, the coefficient becomes lower at higher temperatures for copper, and the value 0.00427 is commonly specified at 0 °C. [53] The extremely low resistivity (high conductivity) of silver is characteristic of metals.
Pourbaix diagram of iron. [1] The Y axis corresponds to voltage potential. In electrochemistry, and more generally in solution chemistry, a Pourbaix diagram, also known as a potential/pH diagram, E H –pH diagram or a pE/pH diagram, is a plot of possible thermodynamically stable phases (i.e., at chemical equilibrium) of an aqueous electrochemical system.
Temperature-programmed reduction is a technique for the characterization of solid materials and is often used in the field of heterogeneous catalysis to find the most efficient reduction conditions, [1] an oxidized catalyst precursor is submitted to a programmed temperature rise while a reducing gas mixture is flowed over it.
In electrochemistry, the Nernst equation is a chemical thermodynamical relationship that permits the calculation of the reduction potential of a reaction (half-cell or full cell reaction) from the standard electrode potential, absolute temperature, the number of electrons involved in the redox reaction, and activities (often approximated by concentrations) of the chemical species undergoing ...
In 1921, solid silver iodide (AgI) was found to have had extraordinary high ionic conductivity at temperatures above 147 °C, AgI changes into a phase that has an ionic conductivity of ~ 1 –1 cm −1. [clarification needed] This high temperature phase of AgI is an example of a superionic conductor.