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A chelating agent is the main component of some rust removal formulations. Citric acid is used to soften water in soaps and laundry detergents. A common synthetic chelator is EDTA. Phosphonates are also well-known chelating agents. Chelators are used in water treatment programs and specifically in steam engineering.
Nitrilotriacetic acid is commercially available as the free acid and as the sodium salt. It is produced from ammonia , formaldehyde , and sodium cyanide or hydrogen cyanide . Worldwide capacity is estimated at 100 thousand tonnes per year. [ 6 ]
This white, water-soluble powder has a wide range of applications across industries. Originally derived from gluconic acid in the 19th century, Sodium Gluconate is known for its chelating properties and is utilized as a chelating agent in various processes. It finds applications in textile, metal surface treatment, cement, and more.
EDDHA or ethylenediamine-N,N ′-bis(2-hydroxyphenylacetic acid) is a chelating agent. Like EDTA, it binds metal ions as a hexadentate ligand, using two amines, two phenolate centers, and two carboxylates as the six binding sites. The complexes are typically anionic. The ligand itself is a white, water-soluble powder.
Dissolution and chelation of metal elements [ edit ] Organic acids have the ability to dissolve soil minerals , and can destroy silicate minerals and iron and aluminum oxides , [ 8 ] so that metal ions are precipitated and complexed with organic complexing agents through ion exchange, surface absorption, and chelation-reaction mechanisms. [ 9 ]
Picolinic acid is a bidentate chelating agent of elements such as chromium, zinc, manganese, copper, iron, and molybdenum in the human body. [5] [6] It is a substrate in the Mitsunobu reaction. In the Hammick reaction, picolinic acid reacts with ketones to give pyridine-2-carbonols: [7] NC 5 H 4 CO 2 H + R 2 C=O → NC 5 H 4 CR 2 (OH) + CO 2
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EDTA is used to solubilize iron(III) in water. In the absence of EDTA or similar chelating agents, ferric ions form insoluble solids and are thus not bioavailable. [1] Together with pentetic acid (DTPA), EDTA is widely used for sequestering metal ions.