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In aqueous solutions, redox potential is a measure of the tendency of the solution to either gain or lose electrons in a reaction. A solution with a higher (more positive) reduction potential than some other molecule will have a tendency to gain electrons from this molecule (i.e. to be reduced by oxidizing this other molecule) and a solution with a lower (more negative) reduction potential ...
Crystalline solids and molecular solids are two opposite extreme cases of materials that exhibit substantially different transport mechanisms. While in atomic solids transport is intra-molecular, also known as band transport, in molecular solids the transport is inter-molecular, also known as hopping transport.
Conductivity or specific conductance of an electrolyte solution is a measure of its ability to conduct electricity. The SI unit of conductivity is siemens per meter (S/m). Conductivity measurements are used routinely in many industrial and environmental applications as a fast, inexpensive and reliable way of measuring the ionic content in a ...
According to Gauss’s law, a conductor at equilibrium carrying an applied current has no charge on its interior.Instead, the entirety of the charge of the conductor resides on the surface, and can be expressed by the equation: = where E is the electric field caused by the charge on the conductor and is the permittivity of the free space.
Pourbaix diagram of iron. [1] The Y axis corresponds to voltage potential. In electrochemistry, and more generally in solution chemistry, a Pourbaix diagram, also known as a potential/pH diagram, E H –pH diagram or a pE/pH diagram, is a plot of possible thermodynamically stable phases (i.e., at chemical equilibrium) of an aqueous electrochemical system.
In practice the molar ionic conductivities are calculated from the measured ion transport numbers and the total molar conductivity. For the cation + = + +, and similarly for the anion. In solutions, where ionic complexation or associaltion are important, two different transport/transference numbers can be defined.
A streaming current and streaming potential are two interrelated electrokinetic phenomena studied in the areas of surface chemistry and electrochemistry. They are an electric current or potential which originates when an electrolyte is driven by a pressure gradient through a channel or porous plug with charged walls. [1] [2] [3]
This, in turn, affects other properties, such as electrical conductivity. When solutions of two oppositely charged polymers (that is, a solution of polycation and one of polyanion) are mixed, a bulk complex (precipitate) is usually formed. This occurs because the oppositely-charged polymers attract one another and bind together.