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Molecular symmetry in physics and chemistry describes the symmetry present in molecules and the classification of molecules according to their symmetry. Molecular symmetry is a fundamental concept in the application of Quantum Mechanics in physics and chemistry, for example it can be used to predict or explain many of a molecule's properties, such as its dipole moment and its allowed ...
In chemistry, molecular symmetry describes the symmetry present in molecules and the classification of these molecules according to their symmetry. Molecular symmetry is a fundamental concept in chemistry, as it can be used to predict or explain many of a molecule's chemical properties , such as whether or not it has a dipole moment , as well ...
The finite group notation used is: Z n: cyclic group of order n, D n: dihedral group isomorphic to the symmetry group of an n–sided regular polygon, S n: symmetric group on n letters, and A n: alternating group on n letters. The character tables then follow for all groups.
Finite spherical symmetry groups are also called point groups in three dimensions. There are five fundamental symmetry classes which have triangular fundamental domains: dihedral, cyclic, tetrahedral, octahedral, and icosahedral symmetry. This article lists the groups by Schoenflies notation, Coxeter notation, [1] orbifold notation, [2] and order.
Molecules containing polar bonds have no molecular polarity if the bond dipoles cancel each other out by symmetry. Polar molecules interact through dipole-dipole intermolecular forces and hydrogen bonds. Polarity underlies a number of physical properties including surface tension, solubility, and melting and boiling points.
A sphere colored to show the 48 fundamental domains of octahedral symmetry. The symmetry number or symmetry order of an object is the number of different but indistinguishable (or equivalent) arrangements (or views) of the object, that is, it is the order of its symmetry group. The object can be a molecule, crystal lattice, lattice, tiling, or ...
An example of a molecular species with square prismatic geometry (a slightly flattened cube) is octafluoroprotactinate(V), [PaF 8] 3–, as found in its sodium salt, Na 3 PaF 8. [6] While local cubic 8-coordination is common in ionic lattices (e.g., Ca 2+ in CaF 2 ), and some 8-coordinate actinide complexes are approximately cubic, there are no ...
Such species belong to the point group D 3h. Molecules where the three ligands are not identical, such as H 2 CO , deviate from this idealized geometry. Examples of molecules with trigonal planar geometry include boron trifluoride (BF 3 ), formaldehyde (H 2 CO), phosgene (COCl 2 ), and sulfur trioxide (SO 3 ).