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Silane (Silicane) is an inorganic compound with chemical formula SiH 4.It is a colorless, pyrophoric, toxic gas with a sharp, repulsive, pungent smell, somewhat similar to that of acetic acid. [5]
Chemical structure of disilane, which is structurally similar to ethane. Silanes are saturated chemical compounds with the empirical formula Si x H y. They are hydrosilanes, a class of compounds that includes compounds with Si−H and other Si−X bonds. All contain tetrahedral silicon and terminal hydrides. They only have Si−H and Si−Si ...
[1] [2] [3] Introduced by Gilbert N. Lewis in his 1916 article The Atom and the Molecule, a Lewis structure can be drawn for any covalently bonded molecule, as well as coordination compounds. [4] Lewis structures extend the concept of the electron dot diagram by adding lines between atoms to represent shared pairs in a chemical bond.
In this type of reaction, carbocations are generated by the action of strong Lewis or Brønsted acids in the presence of hydrosilanes, which then transfer hydride. A typical acid is trifluoroacetic acid (TFA). The reaction is stoichiometric.
A chemical element, often simply called an element, is a type of atom which has a specific number of protons in its atomic nucleus (i.e., a specific atomic number, or Z). [ 1 ] The definitive visualisation of all 118 elements is the periodic table of the elements , whose history along the principles of the periodic law was one of the founding ...
Polysilicon hydrides are polymers containing only silicon and hydrogen. They have the formula () where 0.2 ≤ n ≤ 2.5 and x is the number of monomer units. The polysilicon hydrides are generally colorless or pale-yellow/ocher powders that are easily hydrolyzed and ignite readily in air.
Silicon tetrafluoride or tetrafluorosilane is a chemical compound with the formula Si F 4.This colorless gas is notable for having a narrow liquid range: its boiling point is only 4 °C above its melting point.
The ordered structure forms the β- phase, whereas the higher temperature and more symmetrical disordered structure is called α- phase. The β- phase is about 15% more compact than the α-phase. [8] The silanide ion has C 3v symmetry. The silicon to hydrogen bond length is 1.52 Å and the H-Si-H bond angle is 92.2°, not far off a right angle. [8]