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Phosphorus pentoxide crystallizes in at least four forms or polymorphs.The most familiar one, a metastable form [1] (shown in the figure), comprises molecules of P 4 O 10.Weak van der Waals forces hold these molecules together in a hexagonal lattice (However, in spite of the high symmetry of the molecules, the crystal packing is not a close packing [2]).
DEHPA is prepared through the reaction of phosphorus pentoxide and 2-ethylhexanol: 4 C 8 H 17 OH + P 4 O 10 → 2 [(C 8 H 17 O)PO(OH)] 2 O [(C 8 H 17 O)PO(OH)] 2 O + C 8 H 17 OH → (C 8 H 17 O) 2 PO(OH) + (C 8 H 17 O)PO(OH) 2. These reaction produce a mixture of mono-, di-, and trisubstituted phosphates, from which DEHPA can be isolated based ...
Phosphoryl chloride (commonly called phosphorus oxychloride) is a colourless liquid with the formula P O Cl 3. It hydrolyses in moist air releasing phosphoric acid and fumes of hydrogen chloride . It is manufactured industrially on a large scale from phosphorus trichloride and oxygen or phosphorus pentoxide . [ 4 ]
Phosphorus oxide can refer to: Phosphorus pentoxide (phosphorus(V) oxide, phosphoric anhydride), P 2 O 5; Phosphorus trioxide (phosphorus(III) oxide, phosphorous anhydride), P 2 O 3; Phosphorus tetroxide, P 2 O 4; Several other, less common, oxides of phosphorus, including P 4 O 7, P 4 O 9, and P 2 O 6; Gases: Phosphorus monoxide, PO ...
Elemental phosphorus is distilled out of the furnace and burned with air to produce high-purity phosphorus pentoxide, which is dissolved in water to make phosphoric acid. [22] The thermal process produces phosphoric acid with a very high concentration of P 2 O 5 (about 85%) and a low level of impurities.
White phosphorus, yellow phosphorus or simply tetraphosphorus (P 4) exists as molecules of four phosphorus atoms in a tetrahedral structure, joined by six phosphorus—phosphorus single bonds. [1] The free P 4 molecule in the gas phase has a P-P bond length of r g = 2.1994(3) Å as was determined by gas electron diffraction . [ 2 ]
Unprocessed phosphate rock has a concentration of 1.7–8.7% phosphorus by mass (4–20% phosphorus pentoxide). By comparison, the Earth's crust contains 0.1% phosphorus by mass, [84] and vegetation 0.03–0.2%. [85] Although quadrillions of tons of phosphorus exist in the Earth's crust, [86] these are currently not economically extractable.
It supplies soil with the elements nitrogen and phosphorus in a form usable by plants. Its NPK label is 12-61-0 (12-27-0), meaning that it contains 12% by weight of elemental nitrogen and (nominally) 61% of phosphorus pentoxide P 2 O 5, or 27% of elemental phosphorus.