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In chemistry, a double bond is a covalent bond between two atoms involving four bonding electrons as opposed to two in a single bond. Double bonds occur most commonly between two carbon atoms, for example in alkenes. Many double bonds exist between two different elements: for example, in a carbonyl group between a carbon atom and an oxygen atom ...
A cumulene is a compound having three or more cumulative (consecutive) double bonds. [1] They are analogous to allenes, only having a more extensive chain. The simplest molecule in this class is butatriene (H 2 C=C=C=CH 2), which is also called simply cumulene. Unlike most alkanes and alkenes, cumulenes tend to be rigid, comparable to polyynes.
In fact, the carbon atoms in the single bond need not be of the same hybridization. Carbon atoms can also form double bonds in compounds called alkenes or triple bonds in compounds called alkynes. A double bond is formed with an sp 2-hybridized orbital and a p-orbital that is not involved in the hybridization. A triple bond is formed with an sp ...
Bonds are often shown as a line that connects one atom to another. One line indicates a single bond. Two lines indicate a double bond, and three lines indicate a triple bond. In some structures the atoms in between each bond are specified and shown. However, in some structures, the carbon molecules are not written out specifically.
In 1 H NMR spectroscopy, the hydrogen bonded to the carbon adjacent to double bonds will give a δ H of 4.5–6.5 ppm. The double bond will also deshield the hydrogen attached to the carbons adjacent to sp 2 carbons, and this generates δ H =1.6–2. ppm peaks. [14] Cis/trans isomers are distinguishable due to different J-coupling effect.
Assume that we want to find intersection of two infinite lines in 2-dimensional space, defined as a 1 x + b 1 y + c 1 = 0 and a 2 x + b 2 y + c 2 = 0. We can represent these two lines in line coordinates as U 1 = (a 1, b 1, c 1) and U 2 = (a 2, b 2, c 2). The intersection P′ of two lines is then simply given by [4]
This projection most commonly sights down a carbon-carbon bond, making it a very useful way to visualize the stereochemistry of alkanes. A Newman projection visualizes the conformation of a chemical bond from front to back, with the front atom represented by the intersection of three lines (a dot) and the back atom as a circle.
In stereochemistry, a torsion angle is defined as a particular example of a dihedral angle, describing the geometric relation of two parts of a molecule joined by a chemical bond. [4] [5] Every set of three non-colinear atoms of a molecule defines a half-plane. As explained above, when two such half-planes intersect (i.e., a set of four ...