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Alite is an impure form of tricalcium silicate, Ca 3 SiO 5, sometimes formulated as 3CaO·SiO 2 (C 3 S in cement chemist notation), typically with 3-4% of substituent oxides. [1] It is the major, and characteristic, phase in Portland cement.
Tricalcium silicate is responsible for most of the early strength (first 7 days). [3] Dicalcium silicate, which reacts more slowly, only contributes to late strength. Calcium silicate hydrate (also shown as C-S-H) is a result of the reaction between the silicate phases of Portland cement and water.
Calcium-silicate passive fire protection board being clad around steel structure in order to achieve a fire-resistance rating. Calcium silicate is commonly used as a safe alternative to asbestos for high-temperature insulation materials. Industrial-grade piping and equipment insulation is often fabricated from calcium silicate.
MTA is composed mostly of tricalcium silicate, dicalcium silicate, tricalcium aluminate, and tetracalcium aluminoferrite, with calcium sulfate and bismuth oxide as minor constituents. [3] The later 4 phases vary among the commercial products available.
Cement hydration and strength development mainly depend on two silicate phases: tricalcium silicate (C 3 S) , and dicalcium silicate (C 2 S) . [1] Upon hydration, the main reaction products are calcium silicate hydrates (C-S-H) and calcium hydroxide Ca(OH) 2, written as CH in the cement chemist notation. C-S-H is the phase playing the role of ...
The materials in cement clinker are alite, belite, tricalcium aluminate, and tetracalcium alumino ferrite. The aluminium, iron, and magnesium oxides are present as a flux allowing the calcium silicates to form at a lower temperature, [15] and contribute little to the strength.
The ratio Ca/Si (C/S) and Mg/Si (M/S) decrease from 2 for the dicalcium and dimagnesium silicate reagents to 1.5 for the hydrated silicate products of the hydration reaction. In other term, the C-S-H or the serpentine are less rich in Ca and Mg respectively.
The silicates are responsible for the cement's mechanical properties — the tricalcium aluminate and brownmillerite are essential for the formation of the liquid phase during the sintering process of clinker at high temperature in the kiln. The chemistry of these reactions is not completely clear and is still the object of research. [7]