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Phosphorus pentoxide is a potent dehydrating agent as indicated by the exothermic nature of its hydrolysis producing phosphoric acid: P 4 O 10 + 6 H 2 O → 4 H 3 PO 4 (–177 kJ) However, its utility for drying is limited somewhat by its tendency to form a protective viscous coating that inhibits further dehydration by unspent material.
Phosphorus oxide can refer to: Phosphorus pentoxide (phosphorus(V) oxide, phosphoric anhydride), P 2 O 5; Phosphorus trioxide (phosphorus(III) oxide, phosphorous anhydride), P 2 O 3; Phosphorus tetroxide, P 2 O 4; Several other, less common, oxides of phosphorus, including P 4 O 7, P 4 O 9, and P 2 O 6; Gases: Phosphorus monoxide, PO ...
Unprocessed phosphate rock has a concentration of 1.7–8.7% phosphorus by mass (4–20% phosphorus pentoxide). By comparison, the Earth's crust contains 0.1% phosphorus by mass, [84] and vegetation 0.03–0.2%. [85] Although quadrillions of tons of phosphorus exist in the Earth's crust, [86] these are currently not economically extractable.
Phosphoryl chloride (commonly called phosphorus oxychloride) is a colourless liquid with the formula P O Cl 3. It hydrolyses in moist air releasing phosphoric acid and fumes of hydrogen chloride . It is manufactured industrially on a large scale from phosphorus trichloride and oxygen or phosphorus pentoxide . [ 4 ]
A complex is formed from two equivalents of the conjugate base of DEHPA and one uranyl ion. [6] Complexes of the formula (UO 2) 2 [(O 2 P(OR) 2] 4 also form, and at high concentrations of uranium, polymeric complexes may form. [5] The extractability of Fe 3+ is similar to that of uranium, so it must be reduced to Fe 2+ before the extraction. [5]
Phosphine (IUPAC name: phosphane) is a colorless, flammable, highly toxic compound with the chemical formula P H 3, classed as a pnictogen hydride.Pure phosphine is odorless, but technical grade samples have a highly unpleasant odor like rotting fish, due to the presence of substituted phosphine and diphosphane (P 2 H 4).
Elemental phosphorus is distilled out of the furnace and burned with air to produce high-purity phosphorus pentoxide, which is dissolved in water to make phosphoric acid. [22] The thermal process produces phosphoric acid with a very high concentration of P 2 O 5 (about 85%) and a low level of impurities.
Phosphine oxide is the inorganic compound with the formula H 3 PO. Although stable as a dilute gas, liquid or solid samples are unstable. Unlike many other compounds of the type PO x H y, H 3 PO is rarely discussed and is not even mentioned in major sources on main group chemistry.