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Desulfurization or desulphurisation is a chemical process for the removal of sulfur from a material. [1] The term usually refers to the removal of sulfur from a molecule or a material by hydrogenolysis: [2] R 2 S + 2 H 2 → 2RH + H 2 S. Hydrogen is the ultimate sulfur acceptor. As applied to oil refinery streams, the conversion is known as ...
Hydrodesulfurization or hydrodesulphurisation (Commonwealth English; see spelling differences) (HDS), also called hydrotreatment or hydrotreating, is a catalytic chemical process widely used to remove sulfur (S) from natural gas and from refined petroleum products, such as gasoline or petrol, jet fuel, kerosene, diesel fuel, and fuel oils.
The 4S pathway is a sulfur-specific metabolic pathway of oxidative desulfurization that converts dibenzothiophene (DBT) into 2-hydroxybiphenyl and sulfite.It uses a total of four NADH molecules (three required by DszD to generate FMNH 2 and a fourth to regenerate the FMN-oxide byproduct of DszA) and three molecules of oxygen, thus producing NAD + and water as byproducts.
In oil refineries, that stripped gas is mostly H 2 S, much of which often comes from a sulfur-removing process called hydrodesulfurization. This H 2 S-rich stripped gas stream is then usually routed into a Claus process to convert it into elemental sulfur. In fact, the vast majority of the 64,000,000 metric tons of sulfur produced worldwide in ...
The Wellman–Lord process is a regenerable process to remove sulfur dioxide from flue gas (flue-gas desulfurization) without creating a throwaway sludge product.. In this process, sulfur dioxide from flue gas is absorbed in a sodium sulfite solution in water forming sodium bisulfite; other components of flue gas are not absorbed.
An alternative to removing sulfur from the flue gases after burning is to remove the sulfur from the fuel before or during combustion. Hydrodesulfurization of fuel has been used for treating fuel oils before use. Fluidized bed combustion adds lime to the fuel during combustion. The lime reacts with the SO 2 to form sulfates which become part of ...
In several places there is a need for both electric power and sulfuric acid. A cheap high-sulfur fuel such as petroleum coke can be used for power generation, while the flue gas is cleaned in an SNOX plant producing sulfuric acid. Elemental sulfur is fired in the SNOX plant in order to produce the desired amount of sulfuric acid.
The WSA process can be applied in all industries where sulfur removal presents an issue. The wet catalysis process is used for processing sulfur-containing streams, such as: [1] H 2 S gas from e.g. amine gas treating unit; Off-gas from sour water stripper (SWS) gas; Off-gas from Rectisol; Spent acid from an alkylation unit; Claus process tail gas