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The Schrödinger equation for the electron in a hydrogen atom (or a hydrogen-like atom) is = where is the electron charge, is the position of the electron relative to the nucleus, = | | is the magnitude of the relative position, the potential term is due to the Coulomb interaction, wherein is the permittivity of free space and = + is the 2-body ...
Equations that apply in one picture do not necessarily hold in the others, because time-dependent unitary transformations relate operators in one picture to the analogous operators in the others. Not all textbooks and articles make explicit which picture each operator comes from, which can lead to confusion.
In collapse theories, the Schrödinger equation is supplemented with additional nonlinear and stochastic terms (spontaneous collapses) which localize the wave function in space. The resulting dynamics is such that for microscopic isolated systems, the new terms have a negligible effect; therefore, the usual quantum properties are recovered ...
The step divides space in two parts: x < 0 and x > 0. In any of these parts the potential is constant, meaning the particle is quasi-free, and the solution of the Schrödinger equation can be written as a superposition of left and right moving waves (see free particle)
Position space (also real space or coordinate space) is the set of all position vectors r in Euclidean space, and has dimensions of length; a position vector defines a point in space. (If the position vector of a point particle varies with time, it will trace out a path, the trajectory of a particle.) Momentum space is the set of all momentum ...
For a de Broglie–Bohm theory on curved space with spin, the spin space becomes a vector bundle over configuration space, and the potential in Schrödinger's equation becomes a local self-adjoint operator acting on that space. [42] The field equations for the de Broglie–Bohm theory in the relativistic case with spin can also be given for ...
Since | is a constant ket (the state ket at t = 0), and since the above equation is true for any constant ket in the Hilbert space, the time evolution operator must obey the equation = (). If the Hamiltonian is independent of time, the solution to the above equation is [ note 1 ] U ( t ) = e − i H t / ℏ . {\displaystyle U(t)=e^{-iHt/\hbar }.}
and this is the Schrödinger equation. Note that the normalization of the path integral needs to be fixed in exactly the same way as in the free particle case. An arbitrary continuous potential does not affect the normalization, although singular potentials require careful treatment.