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(9) A second significant side reaction in reactions of ketones and aldehydes is selanylation of the intermediate selenoxide. This process leads to elimination products retaining a carbon-selenium bond, [ 16 ] and is more difficult to prevent than the seleno-Pummerer reaction.
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His discovery, made widely known through its financial success, greatly increased interest in organic chemistry. [9] A crucial breakthrough for organic chemistry was the concept of chemical structure, developed independently in 1858 by both Friedrich August Kekulé and Archibald Scott Couper. [10]
In organic chemistry, syn-and anti-addition are different ways in which substituent molecules can be added to an alkene (R 2 C=CR 2) or alkyne (RC≡CR).The concepts of syn and anti addition are used to characterize the different reactions of organic chemistry by reflecting the stereochemistry of the products in a reaction.
Wiley-Interscience, 3rd edition, 1999, ISBN 0-471-16019-9; Wiley-Interscience, 4th edition, 2007, ISBN 0-471-69754-0; Wiley-Interscience, 5th edition, 2014, ISBN 9781118057483; Description: A comprehensive reference for the usage of protecting groups in organic synthesis. Importance: A reference publication.