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So, CAC cement must not be confused with calcium sulfo-aluminate (CSA) cement containing calcium sulfate and invented later in 1936. [6] The main constituent, and also the most reactive phase, of calcium aluminate cements is the monocalcium aluminate (CaAl 2 O 4 = CaO · Al 2 O 3, also written as CA in the cement chemist notation).
AFm form inter alia when tricalcium aluminate 3CaO·Al 2 O 3, or C 3 A in CCN, reacts with dissolved calcium sulfate (CaSO 4), or calcium carbonate (CaCO 3). As the sulfate form is the dominant one in AFm phases in the hardened cement paste (HCP) in concrete, AFm is often simply referred to as Aluminate Ferrite monosulfate or calcium aluminate ...
Calcium aluminate cements are hydraulic cements made primarily from limestone and bauxite. The active ingredients are monocalcium aluminate CaAl 2 O 4 (CaO · Al 2 O 3 or CA in cement chemist notation, CCN) and mayenite Ca 12 Al 14 O 33 (12 CaO · 7 Al 2 O 3, or C 12 A 7 in CCN). Strength forms by hydration to calcium aluminate hydrates.
In calcium aluminate cements, it exists as a solid solution in which the amount of minor elements depends upon the bulk composition of the cement. A typical composition [ 4 ] is Ca 0.93 Al 1.94 Fe 0.11 Si 0.02 O 4 .
Calcium aluminates phase diagram Crystal structure of dodecacalcium hepta-aluminate, 12CaO·7Al 2 O 3 (C 12 A 7). [1] Calcium aluminates are a range of materials [2] obtained by heating calcium oxide and aluminium oxide together at high temperatures. They are encountered in the manufacture of refractories and cements.
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