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For example, germanium was called eka-silicon until its discovery in 1886, and rhenium was called dvi-manganese before its discovery in 1926. The eka-prefix was used by other theorists, and not only in Mendeleev's own predictions. Before the discovery, francium was referred to as eka-caesium, and astatine as eka-iodine.
In 1871, Mendeleev predicted this missing element would occupy the empty place below manganese and have similar chemical properties. Mendeleev gave it the provisional name eka-manganese (from eka, the Sanskrit word for one) because it was one place down from the known element manganese. [6]
41 of the 118 known elements have names associated with, or specifically named for, places around the world or among astronomical objects. 32 of these have names tied to the places on Earth, and the other nine are named after to Solar System objects: helium for the Sun; tellurium for the Earth; selenium for the Moon; mercury (indirectly), uranium, neptunium and plutonium after their respective ...
At least rhenium was called dvi-manganese (because eka-manganese, i.e. technetium, wasn't known either). Icek~enwiki ( talk ) 00:22, 15 January 2016 (UTC) [ reply ] There is and was no reason to use the higher numbers when the lower number could be used; hence you might see element 115 called eka-bismuth today, but certainly not dvi-antimony.
shows the increasing stability of the lower oxidation state as atomic number increases. The very large value for the manganese couple is a consequence of the fact that octahedral manganese(II) has zero crystal field stabilization energy (CFSE) but manganese(III) has 3 units of CFSE. [13]
Four allotropes (structural forms) of solid manganese are known, labeled α, β, γ and δ, and occurring at successively higher temperatures. All are metallic, stable at standard pressure, and have a cubic crystal lattice, but they vary widely in their atomic structures. [18] [19] [20] Alpha manganese (α-Mn) is the equilibrium phase at room ...
Manganese is also important in photosynthetic oxygen evolution in chloroplasts in plants. The oxygen-evolving complex (OEC) is a part of photosystem II contained in the thylakoid membranes of chloroplasts; it is responsible for the terminal photooxidation of water during the light reactions of photosynthesis , and has a metalloenzyme core ...
Manganese nodules are essentially composed of hydrated phyllomanganates. These are layered Mn-oxide minerals with interlayers containing water molecules in variable quantities. They strongly interact with trace metals (Co 2+, Ni 2+) because of the octahedral vacancies present in their layers. The particular properties of phyllomanganates ...