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The reversible expansion of an ideal gas can be used as an example of an isobaric process. [3] Of particular interest is the way heat is converted to work when expansion is carried out at different working gas/surrounding gas pressures. This picture has been created using open access software.
A number of materials contract on heating within certain temperature ranges; this is usually called negative thermal expansion, rather than "thermal contraction".For example, the coefficient of thermal expansion of water drops to zero as it is cooled to 3.983 °C (39.169 °F) and then becomes negative below this temperature; this means that water has a maximum density at this temperature, and ...
An enthalpy–entropy chart, also known as the H–S chart or Mollier diagram, plots the total heat against entropy, [1] describing the enthalpy of a thermodynamic system. [2] A typical chart covers a pressure range of 0.01–1000 bar, and temperatures up to 800 degrees Celsius. [3] It shows enthalpy in terms of internal energy , pressure and ...
The four points in the graph indicate the crank angle in degrees. [7] The adiabatic Stirling cycle is similar to the idealized Stirling cycle; however, the four thermodynamic processes are slightly different (see graph above): 180° to 270°, pseudo-isothermal expansion. The expansion space is heated externally, and the gas undergoes near ...
Thermodynamics. Thermodynamic diagrams are diagrams used to represent the thermodynamic states of a material (typically fluid) and the consequences of manipulating this material. For instance, a temperature– entropy diagram (T–s diagram) may be used to demonstrate the behavior of a fluid as it is changed by a compressor.
A thermodynamic cycle consists of linked sequences of thermodynamic processes that involve transfer of heat and work into and out of the system, while varying pressure, temperature, and other state variables within the system, and that eventually returns the system to its initial state. [1] In the process of passing through a cycle, the working ...
Graph of temperature of phases of water heated from −100 °C to 200 °C – the dashed line example shows that melting and heating 1 kg of ice at −50 °C to water at 40 °C needs 600 kJ. The specific heat capacities of gases can be measured at constant volume, by enclosing the sample in a rigid container.
The isothermal–isobaric ensemble (constant temperature and constant pressure ensemble) is a statistical mechanical ensemble that maintains constant temperature and constant pressure applied. It is also called the -ensemble, where the number of particles is also kept as a constant. This ensemble plays an important role in chemistry as chemical ...