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Perfluorohexane (C 6 F 14), or tetradecafluorohexane, is a fluorocarbon.It is a derivative of hexane in which all the hydrogen atoms are replaced by fluorine atoms. It is used in one formulation of the electronic cooling liquid/insulator Fluorinert for low-temperature applications due to its low boiling point of 56 °C and freezing point of −90 °C.
Fluorinert is the trademarked brand name for the line of electronics coolant liquids sold commercially by 3M.As perfluorinated compounds (PFCs), all Fluorinert variants have an extremely high global warming potential (GWP), [1] so should be used with caution (see below).
The process proceeds at low voltage (5 – 6 V) so that free fluorine is not liberated. The choice of substrate is restricted as ideally it should be soluble in hydrogen fluoride. Ethers and tertiary amines are typically employed. To make perfluorohexane, trihexylamine is used, for example: N(C 6 H 13) 3 + 45 HF → 3 C 6 F 14 + NF 3 + 42 H 2
A water sample is measured as part of a PFAS drinking water treatment experiment, Tuesday, Feb. 14, 2023, at the U.S. Environmental Protection Agency Center For Environmental Solutions and ...
They are widely used in the electronics, cosmetics, and pharmaceutical industries, as well as in refrigeration when combined with other gases. PFCs were commonly used as fire extinguishants in the past and are still found in older fire protection systems. They are also a by-product of the aluminium smelting process.
Perfluorohexanesulfonic acid (PFHxS) (conjugate base perfluorohexanesulfonate) is a synthetic chemical compound.It is one of many compounds collectively known as per- and polyfluoroalkyl substances (PFASs).
The Fowler process is typically done in two stages, the first stage being fluorination of cobalt(II) fluoride to cobalt(III) fluoride.. 2 CoF 2 + F 2 → 2 CoF 3. During the second stage, in this instance to make perfluorohexane, the hydrocarbon feed is introduced and is fluorinated by the cobalt(III) fluoride, which is converted back to cobalt(II) fluoride for reuse.
Perfluoro(2-methyl-3-pentanone) is a fluorinated ketone with the structural formula CF 3 CF 2 C(=O)CF(CF 3) 2, a fully-fluorinated analog of ethyl isopropyl ketone.It is used as an electronics coolant liquid and fire protection fluid sold commercially by 3M under brand names such as Novec 1230, Novec 649, and FK-5-1-12.