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The efficiency of a thermoelectric device for electricity generation is given by , defined as =.. The maximum efficiency of a thermoelectric device is typically described in terms of its device figure of merit where the maximum device efficiency is approximately given by [7] = + ¯ + ¯ +, where is the fixed temperature at the hot junction, is the fixed temperature at the surface being cooled ...
A thermoelectric battery stores energy when charged by converting heat into chemical energy and produces electricity when discharged. Such systems potentially offer an alternative means of disposing of waste heat from plants that burn fossil fuels and/or nuclear energy.
The performance of thermoelectric materials can be evaluated by the figure of merit, = /, in which is the Seebeck coefficient, is the electrical conductivity and is the thermal conductivity. In order to improve the thermoelectric performance of materials, the power factor ( S 2 σ {\displaystyle S^{2}\sigma } ) needs to be maximized and the ...
Only a few known materials to date are identified as thermoelectric materials. Most thermoelectric materials today have a zT, the figure of merit, value of around 1, such as in bismuth telluride (Bi 2 Te 3) at room temperature and lead telluride (PbTe) at 500–700 K. However, in order to be competitive with other power generation systems, TEG ...
Bismuth telluride (Bi 2 Te 3) is a gray powder that is a compound of bismuth and tellurium also known as bismuth(III) telluride. It is a semiconductor, which, when alloyed with antimony or selenium, is an efficient thermoelectric material for refrigeration or portable power generation.
The Seebeck coefficient (also known as thermopower, [1] thermoelectric power, and thermoelectric sensitivity) of a material is a measure of the magnitude of an induced thermoelectric voltage in response to a temperature difference across that material, as induced by the Seebeck effect. [2]
Bismuth selenide is a semiconductor and a thermoelectric material. [4] While stoichiometric bismuth selenide should be a semiconductor with a gap of 0.3 eV, naturally occurring selenium vacancies act as electron donors, so Bi 2 Se 3 is intrinsically n-type. [5] [6] [7] Bismuth selenide has a topologically insulating ground-state. [8]
A trigonal Te with the space group of P3 1 21 can transfer into a topological insulator phase, which is suitable for thermoelectric material. Though often not considered as a thermoelectric material alone, polycrystalline tellurium does show great thermoelectric performance with the thermoelectric figure of merit, zT, as high as 1.0, which is ...
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