Search results
Results From The WOW.Com Content Network
Anhydrous aluminium chloride is a powerful Lewis acid, capable of forming Lewis acid-base adducts with even weak Lewis bases such as benzophenone and mesitylene. [14] It forms tetrachloroaluminate ([AlCl 4] −) in the presence of chloride ions. Aluminium chloride reacts with calcium and magnesium hydrides in tetrahydrofuran forming ...
Lewis structure of a water molecule. Lewis structures – also called Lewis dot formulas, Lewis dot structures, electron dot structures, or Lewis electron dot structures (LEDs) – are diagrams that show the bonding between atoms of a molecule, as well as the lone pairs of electrons that may exist in the molecule.
The most common Lewis bases are anions. The strength of Lewis basicity correlates with the pK a of the parent acid: acids with high pK a 's give good Lewis bases. As usual, a weaker acid has a stronger conjugate base. Examples of Lewis bases based on the general definition of electron pair donor include: simple anions, such as H − and F −
Main page; Contents; Current events; Random article; About Wikipedia; Contact us; Pages for logged out editors learn more
Common Lewis acid catalysts are based on main group metals such as aluminum, boron, silicon, and tin, as well as many early (titanium, zirconium) and late (iron, copper, zinc) d-block metals. The metal atom forms an adduct with a lone-pair bearing electronegative atom in the substrate, such as oxygen (both sp 2 or sp 3 ), nitrogen , sulfur ...
3, formed by the reaction of aluminium and iodine [4] or the action of HI on Al metal. The hexahydrate is obtained from a reaction between metallic aluminum or aluminum hydroxide with hydrogen iodide or hydroiodic acid. Like the related chloride and bromide, AlI 3 is a strong Lewis acid and will absorb water from the
Get AOL Mail for FREE! Manage your email like never before with travel, photo & document views. Personalize your inbox with themes & tabs. You've Got Mail!
For similar reasons, anhydrous aluminium salts cannot be made by heating their "hydrates": hydrated aluminium chloride is in fact not AlCl 3 ·6H 2 O but [Al(H 2 O) 6]Cl 3, and the Al–O bonds are so strong that heating is not sufficient to break them and form Al–Cl bonds instead: [2] 2[Al(H 2 O) 6]Cl 3 Al 2 O 3 + 6 HCl + 9 H 2 O