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The entropy of vaporization of XeF 6 at its boiling point has the extraordinarily high value of 136.9 J/(K·mol). [4] The characteristic of those liquids to which Trouton’s rule cannot be applied is their special interaction between molecules, such as hydrogen bonding. The entropy of vaporization of water and ethanol shows positive deviance ...
Toluene (/ ˈ t ɒ l. j u iː n /), also known as toluol (/ ˈ t ɒ l. j u. ɒ l , - ɔː l , - oʊ l / ), is a substituted aromatic hydrocarbon [ 15 ] with the chemical formula C 6 H 5 CH 3 , often abbreviated as PhCH 3 , where Ph stands for the phenyl group.
High vapor pressures indicate a high volatility, while high boiling points indicate low volatility. Vapor pressures and boiling points are often presented in tables and charts that can be used to compare chemicals of interest. Volatility data is typically found through experimentation over a range of temperatures and pressures.
The boiling point elevation is a colligative property, which means that boiling point elevation is dependent on the number of dissolved particles but not their identity. [1] It is an effect of the dilution of the solvent in the presence of a solute. It is a phenomenon that happens for all solutes in all solutions, even in ideal solutions, and ...
Triple point: 178.15 K (−94.99 °C), ? Pa Critical point: 591.79 K (318.64 °C), 4.109 MPa Std enthalpy change of fusionΔ fus H o: 6.636 kJ/mol Std entropy change of fusionΔ fus S o: 37.25 J/(mol·K) Std enthalpy change of vaporizationΔ vap H o: 38.06 kJ/mol Std entropy change of vaporizationΔ vap S o: 87.30 J/(mol·K) Solid properties ...
When the molecular size becomes that of a macromolecule, polymer, or otherwise very large, the compound often decomposes at high temperature before the boiling point is reached. Another factor that affects the normal boiling point of a compound is the polarity of its molecules. As the polarity of a compound's molecules increases, its normal ...
The boiling point is an important property because it determines the speed of evaporation. Small amounts of low-boiling-point solvents like diethyl ether , dichloromethane , or acetone will evaporate in seconds at room temperature, while high-boiling-point solvents like water or dimethyl sulfoxide need higher temperatures, an air flow, or the ...
The autoignition temperature or self-ignition temperature, often called spontaneous ignition temperature or minimum ignition temperature (or shortly ignition temperature) and formerly also known as kindling point, of a substance is the lowest temperature at which it spontaneously ignites in a normal atmosphere without an external source of ignition, such as a flame or spark. [1]