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For a fixed mass of an ideal gas kept at a fixed temperature, pressure and volume are inversely proportional. [2] Boyle's law is a gas law, stating that the pressure and volume of a gas have an inverse relationship. If volume increases, then pressure decreases and vice versa, when the temperature is held constant.
Isotherms of an ideal gas for different temperatures. The curved lines are rectangular hyperbolae of the form y = a/x. They represent the relationship between pressure (on the vertical axis) and volume (on the horizontal axis) for an ideal gas at different temperatures: lines that are farther away from the origin (that is, lines that are nearer to the top right-hand corner of the diagram ...
= molar mass of Earth's air: 0.0289644 kg/mol The value of subscript b ranges from 0 to 6 in accordance with each of seven successive layers of the atmosphere shown in the table below. The reference value for ρ b for b = 0 is the defined sea level value, ρ 0 = 1.2250 kg/m 3 or 0.0023768908 slug/ft 3 .
The laws describing the behaviour of gases under fixed pressure, volume, amount of gas, and absolute temperature conditions are called gas laws.The basic gas laws were discovered by the end of the 18th century when scientists found out that relationships between pressure, volume and temperature of a sample of gas could be obtained which would hold to approximation for all gases.
R is the gas constant, which must be expressed in units consistent with those chosen for pressure, volume and temperature. For example, in SI units R = 8.3145 J⋅K −1 ⋅mol −1 when pressure is expressed in pascals, volume in cubic meters, and absolute temperature in kelvin. The ideal gas law is an extension of experimentally discovered ...
In gas mixtures, e.g. air, the partial volume allows focusing on one particular gas component, e.g. oxygen. It can be approximated both from partial pressure and molar fraction: [4] = = V X is the partial volume of any individual gas component (X) V tot is the total volume in gas mixture; P X is the partial pressure of gas X
The standard unit of specific volume is cubic meters per kilogram (m 3 /kg), but other units include ft 3 /lb, ft 3 /slug, or mL/g. [1] Specific volume for an ideal gas is related to the molar gas constant (R) and the gas's temperature (T), pressure (P), and molar mass (M): =
The ideal gas equation can be rearranged to give an expression for the molar volume of an ideal gas: = = Hence, for a given temperature and pressure, the molar volume is the same for all ideal gases and is based on the gas constant: R = 8.314 462 618 153 24 m 3 ⋅Pa⋅K −1 ⋅mol −1, or about 8.205 736 608 095 96 × 10 −5 m 3 ⋅atm⋅K ...