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Frankland's original synthesis of diethylzinc involves the reaction of ethyl iodide with zinc metal. The zinc must be activated to facilitate this redox reaction. One of such activated form of zinc employed by Frankland is zinc-copper couple. [5]
After his return to England Frankland achieved the synthesis of diethylzinc and dimethylzinc by the reaction of ethyl iodide and methyl iodide with metallic zinc. [17] The theoretical deductions Frankland drew from considering these bodies were even more interesting and important than the bodies themselves.
Edward Frankland first reported the compound in 1848 from zinc and ethyl iodide, the first organozinc compound discovered. [2] [3] He improved the synthesis by using diethyl mercury as starting material. [4]
Zinc phosphate is an inorganic compound with the formula Zn 3 (PO 4) 2. This white powder is widely used as a corrosion resistant coating on metal surfaces either as part of an electroplating process or applied as a primer pigment (see also red lead ).
Blum–Ittah aziridine synthesis; Bodroux reaction; Bodroux–Chichibabin aldehyde synthesis; Bogert–Cook synthesis; Bohlmann-Rahtz pyridine synthesis; Bohn–Schmidt reaction; Boord olefin synthesis; Borodin reaction; Borsche–Drechsel cyclization; Bosch–Meiser urea process; Bosch reaction; Bouveault aldehyde synthesis; Bouveault–Blanc ...
The term phosphate is also used in organic chemistry for the functional groups that result when one or more of the hydrogens are replaced by bonds to other groups. These acids, together with their salts and esters , include some of the best-known compounds of phosphorus, of high importance in biochemistry , mineralogy , agriculture , pharmacy ...
The oxygen on an aldehyde or ketone coordinates to the zinc to form the six-member chair like transition state 3. A rearrangement occurs in which zinc switches to the aldehyde or ketone oxygen and a carbon-carbon bond is formed 4. Acid workup 5,6 removes zinc to yield zinc(II) salts and a β-hydroxy-ester 7. [5]
Zinc is a strong reducing agent with a standard redox potential of −0.76 V. Pure zinc tarnishes rapidly in air, rapidly forming a passive layer. The composition of this layer can be complex, but one constituent is probably basic zinc carbonate, Zn 5 (OH) 6 CO 3. [8] The reaction of zinc with water is slowed by this passive layer.