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Phosphorus pentoxide crystallizes in at least four forms or polymorphs.The most familiar one, a metastable form [1] (shown in the figure), comprises molecules of P 4 O 10.Weak van der Waals forces hold these molecules together in a hexagonal lattice (However, in spite of the high symmetry of the molecules, the crystal packing is not a close packing [2]).
In chemistry, the oxidation state, or oxidation number, is the hypothetical charge of an atom if all of its bonds to other atoms were fully ionic. It describes the degree of oxidation (loss of electrons) of an atom in a chemical compound. Conceptually, the oxidation state may be positive, negative or zero.
The oxidation states are also maintained in articles of the elements (of course), and systematically in the table {{Infobox element/symbol-to-oxidation-state}}
Phosphorus forms a wide range of sulfides, where the phosphorus can be in P(V), P(III) or other oxidation states. The three-fold symmetric P 4 S 3 is used in strike-anywhere matches. P 4 S 10 and P 4 O 10 have analogous structures. [48] Mixed oxyhalides and oxyhydrides of phosphorus(III) are almost unknown.
Pyrophosphoric acid. In chemistry, a phosphoric acid, in the general sense, is a phosphorus oxoacid in which each phosphorus (P) atom is in the oxidation state +5, and is bonded to four oxygen (O) atoms, one of them through a double bond, arranged as the corners of a tetrahedron.
Protactinium oxides are known for the metal oxidation states +2, +4 and +5. The most stable is white pentoxide Pa 2 O 5, which can be produced by igniting protactinium(V) hydroxide in air at a temperature of 500 °C. [10] Its crystal structure is cubic, and the chemical composition is often non-stoichiometric, described as PaO 2.25. Another ...
Antimony tetroxide is a mixed-valence compound, where half of the antimony atoms are in the +3 oxidation state, and the other half are in the +5 oxidation state. It is expected that moscovium will have an inert-pair effect for both the 7s and the 7p 1/2 electrons, as the binding energy of the lone 7p 3/2 electron is noticeably lower than that ...
It has many polymorphic forms all based largely on octahedrally coordinated niobium atoms. [3] [4] The polymorphs are identified with a variety of prefixes.[3] [4] The form most commonly encountered is monoclinic H-Nb 2 O 5, which has a complex structure with a unit cell containing 28 niobium atoms and 70 oxygen, where 27 of the niobium atoms are octahedrally coordinated and one tetrahedrally. [5]