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Lithium methoxide is a compound with formula LiCH 3 O. It is the lithium salt of methanol.Like other alkali metal alkoxides, lithium methoxide adopts a polymeric structure [1] Its solubility in common polar aprotic solvents like THF is low; however, it is soluble in methanol and is available commercially as a 10% solution.
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The hydroxymethyl group is a substituent with the structural formula −CH 2 −OH.It consists of a methylene bridge (−CH 2 − unit) bonded to a hydroxyl group (−OH).This makes the hydroxymethyl group an alcohol.
Sodium methoxide is prepared by treating methanol with sodium: 2 Na + 2 CH 3 OH → 2 CH 3 ONa + H 2. The reaction is so exothermic that ignition is possible. The resulting solution, which is colorless, is often used as a source of sodium methoxide, but the pure material can be isolated by evaporation followed by heating to remove residual methanol.
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Methoxymethanol forms spontaneously when a water solution of formaldehyde and methanol are mixed. [3] [1] or when formaldehyde is bubbled through methanol.[4]In space methoxymethanol can form when methanol radicals (CH 2 OH or CH 3 O) react.
MAO is well known as catalyst activator for olefin polymerizations by homogeneous catalysis.In traditional Ziegler–Natta catalysis, supported titanium trichloride is activated by treatment with trimethylaluminium (TMA).
The structure of a typical methoxy group. In organic chemistry, a methoxy group is the functional group consisting of a methyl group bound to oxygen.This alkoxy group has the formula R−O−CH 3.