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  2. State function - Wikipedia

    en.wikipedia.org/wiki/State_function

    In the thermodynamics of equilibrium, a state function, function of state, or point function for a thermodynamic system is a mathematical function relating several state variables or state quantities (that describe equilibrium states of a system) that depend only on the current equilibrium thermodynamic state of the system [1] (e.g. gas, liquid, solid, crystal, or emulsion), not the path which ...

  3. Thermodynamic equilibrium - Wikipedia

    en.wikipedia.org/wiki/Thermodynamic_equilibrium

    Global thermodynamic equilibrium (GTE) means that those intensive parameters are homogeneous throughout the whole system, while local thermodynamic equilibrium (LTE) means that those intensive parameters are varying in space and time, but are varying so slowly that, for any point, one can assume thermodynamic equilibrium in some neighborhood ...

  4. Thermodynamic system - Wikipedia

    en.wikipedia.org/wiki/Thermodynamic_system

    Thermodynamic equilibrium is characterized not only by the absence of any flow of mass or energy, but by “the absence of any tendency toward change on a macroscopic scale.” [2] Equilibrium thermodynamics, as a subject in physics, considers macroscopic bodies of matter and energy in states of internal thermodynamic equilibrium.

  5. Phase rule - Wikipedia

    en.wikipedia.org/wiki/Phase_rule

    In thermodynamics, the phase rule is a general principle governing multi-component, multi-phase systems in thermodynamic equilibrium.For a system without chemical reactions, it relates the number of freely varying intensive properties (F) to the number of components (C), the number of phases (P), and number of ways of performing work on the system (N): [1] [2] [3]: 123–125

  6. Critical point (thermodynamics) - Wikipedia

    en.wikipedia.org/wiki/Critical_point...

    The existence of a critical point was first discovered by Charles Cagniard de la Tour in 1822 [10] [11] and named by Dmitri Mendeleev in 1860 [12] [13] and Thomas Andrews in 1869. [14] Cagniard showed that CO 2 could be liquefied at 31 °C at a pressure of 73 atm, but not at a slightly higher temperature, even under pressures as high as 3000 atm.

  7. Markov chain - Wikipedia

    en.wikipedia.org/wiki/Markov_chain

    This is an equivalence relation which yields a set of communicating classes. A class is closed if the probability of leaving the class is zero. A Markov chain is irreducible if there is one communicating class, the state space. A state i has period k if k is the greatest common divisor of the number of transitions by which i can be reached ...

  8. Homogeneity (physics) - Wikipedia

    en.wikipedia.org/wiki/Homogeneity_(physics)

    In physics, a homogeneous material or system has the same properties at every point; it is uniform without irregularities. [ 1 ] [ 2 ] A uniform electric field (which has the same strength and the same direction at each point) would be compatible with homogeneity (all points experience the same physics).

  9. Thermodynamic equations - Wikipedia

    en.wikipedia.org/wiki/Thermodynamic_equations

    The equilibrium state of a thermodynamic system is described by specifying its "state". The state of a thermodynamic system is specified by a number of extensive quantities , the most familiar of which are volume , internal energy , and the amount of each constituent particle ( particle numbers ).