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Phosphonic esters are prepared using the Michaelis–Arbuzov reaction. For example, methyl iodide catalyses the conversion of trimethylphosphite to the phosphonate ester dimethyl methylphosphonate: P(OMe) 3 → MePO(OMe) 2. These esters can be hydrolysed to the acid (Me = methyl): MePO(OMe) 2 + H 2 O → MePO(OH) 2 + 2 MeOH
Alkyl phosphite esters are used in the Perkow reaction for the formation of vinyl phosphonates, and in the Michaelis–Arbuzov reaction to form phosphonates. Aryl phosphite esters may not undergo these reactions and hence are commonly used as stabilizers in halogen-bearing polymers such as PVC. Autoxidation of a keto steroid with oxygen to the ...
Phosphonates are esters of phosphonic acid and have the general formula RP(=O)(OR') 2. Phosphonates have many technical applications, a well-known member being glyphosate, better known as Roundup. With the formula (HO) 2 P(O)CH 2 NHCH 2 CO 2 H, this derivative of glycine is one of the most widely used herbicides.
Organophosphate flame retardants are part of a wider family of phosphorus-based agents which include organic phosphonate and phosphinate esters, in addition to inorganic salts. [ 56 ] [ 57 ] When some prominent brominated flame retardant were banned in the early 2000s phosphorus-based agents were promoted as safer replacements.
[2] [3] This reaction is widely used for the synthesis of various phosphonates, phosphinates, and phosphine oxides. Several reviews have been published. [4] [5] The reaction also occurs for coordinated phosphite ligands, as illustrated by the demethylation of {(C 5 H 5)Co[(CH 3 O) 3 P] 3} 2+ to give {(C 5 H 5)Co[(CH 3 O) 2 PO] 3} −, which is ...
Triethyl phosphonoacetate is a reagent for organic synthesis used in the Horner-Wadsworth-Emmons reaction (HWE) or the Horner-Emmons modification. Triethyl phosphonoacetate can be added dropwise to sodium methoxide solution to prepare a phosphonate anion. It has an acidic proton that can easily be abstracted by a weak base.
Pages in category "Phosphonate esters" The following 18 pages are in this category, out of 18 total. This list may not reflect recent changes. A. Armine (chemical) B.
Triethyl phosphite (TEP) is an organophosphorus compound, specifically a phosphite ester, with the formula P(OCH 2 CH 3) 3, often abbreviated P(OEt) 3. It is a colorless, malodorous liquid. It is used as a ligand in organometallic chemistry and as a reagent in organic synthesis.