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Selenium is found in metal sulfide ores, where it substitutes for sulfur. Commercially, selenium is produced as a byproduct in the refining of these ores. Minerals that are pure selenide or selenate compounds are rare. The chief commercial uses for selenium today are glassmaking and pigments. Selenium is a semiconductor and is used in photocells.
The sulfoxide in sulfur chemistry is represented in selenium chemistry by the selenoxides (formula RSe(O)R), which are intermediates in organic synthesis, as illustrated by the selenoxide elimination reaction. Consistent with trends indicated by the double bond rule, selenoketones, R(C=Se)R, and selenaldehydes, R(C=Se)H, are rarely observed.
Simplest is the material selenium sulfide, which has medicinal properties. It adopt the diverse structures of elemental sulfur but with some S atoms replaced by Se. Other inorganic selenide sulfide compounds occur as minerals and as pigments. One example is antimony selenosulfide.
In organic chemistry, a sulfoxide, also called a sulphoxide, is an organosulfur compound containing a sulfinyl (>SO) functional group attached to two carbon atoms. It is a polar functional group. Sulfoxides are oxidized derivatives of sulfides .
The simplest sulfoxide, dimethyl sulfoxide, is a common solvent; a common sulfone is sulfolane. Sulfonic acids are used in many detergents. Compounds with carbon–sulfur multiple bonds are uncommon, an exception being carbon disulfide, a volatile colorless liquid that is structurally similar to carbon dioxide.
Selenium sulfide can refer to either of the following: Selenium disulfide, SeS 2; Selenium hexasulfide, Se 2 S 6 This page was last edited on 27 January ...
As indicated by the fact that only a few thousand tons of selenium are produced annually, the subset of selenium compounds called selenides find few applications. Commercially significant is zinc selenide, which is used in some infrared optics. Cadmium selenide is a pigment but its use has been declining because of environmental considerations.
Carbonyl selenide can be produced by treating selenium with carbon monoxide in the presence of amines. [3]It is used in organoselenium chemistry as a means of incorporating selenium into organic compounds, e.g. for the preparation of selenocarbamates (O-selenocarbamates R−O−C(=Se)−NR'R" and Se-selenocarbamates, R−Se−C(=O)−NR'R", where R is organyl and R' and R" are any group ...