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Le Chatelier–Braun principle analyzes the qualitative behaviour of a thermodynamic system when a particular one of its externally controlled state variables, say , changes by an amount , the 'driving change', causing a change , the 'response of prime interest', in its conjugate state variable , all other externally controlled state variables remaining constant.
Henry Louis Le Chatelier [1] (French pronunciation: [ɑ̃ʁi lwi lə ʃɑtəlje]; 8 October 1850 – 17 September 1936) was a French chemist of the late 19th and early 20th centuries. He devised Le Chatelier's principle, used by chemists and chemical engineers to predict the effect a changing condition has on a system in chemical equilibrium.
According to Le Chatelier's principle, the addition of acetate ions from sodium acetate will suppress the ionization of acetic acid and shift its equilibrium to the left. Thus the percent dissociation of the acetic acid will decrease, and the pH of the solution will increase.
The front page quotes the motto of J. Willard Gibbs: "Mathematics is a language."The book begins with this statement: The existence of analogies between central features of various theories implies the existence of a general theory which underlies the particular theories and unifies them with respect to those central features.
Le Châtelier's principle (1884) predicts the behavior of an equilibrium system when changes to its reaction conditions occur. If a dynamic equilibrium is disturbed by changing the conditions, the position of equilibrium moves to partially reverse the change. For example, adding more S (to the chemical reaction above) from the outside will ...
Le Chatelier's principle – a nineteenth-century principle that defied a mathematical proof until the advent of the Fluctuation Theorem. Crooks fluctuation theorem – an example of transient fluctuation theorem relating the dissipated work in nonequilibrium transformations to free energy differences.
Henry Louis Le Chatelier develops Le Chatelier's principle, which explains the response of dynamic chemical equilibria to external stresses. [3] Paul Vieille invents Poudre B, the first smokeless powder for firearms. [4]
(a) Le Chatelier's principle also states that when there is an external constraint on a system, a behavioural shift in the system occurs so as to annul the effect of that change. (b) Where a shock initially induces positive feedback (such as thermal runaway), the new equilibrium can be far from the old one, and can take a long time to reach.