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Vanadium is a trace metal that is relatively abundant in the Earth (~100 part per million in the upper crust). [1] Vanadium is mobilized from minerals through weathering and transported to the ocean. Vanadium can enter the atmosphere through wind erosion and volcanic emissions [1] and will remain there until it is removed by precipitation. [1]
The Pourbaix diagram for vanadium in water, which shows the redox potentials between various vanadium species in different oxidation states [39] Vanadium(V) forms various peroxo complexes, most notably in the active site of the vanadium-containing bromoperoxidase enzymes. The species VO(O 2)(H 2 O) 4 + is stable in acidic solutions.
Water carried into the mantle eventually returns to the surface in eruptions at mid-ocean ridges and hotspots. [131]: 646 Estimates of the amount of water in the mantle range from 1 ⁄ 4 to 4 times the water in the ocean. [131]: 630–634 The deep carbon cycle is the movement of carbon through the Earth's mantle and core.
The Earth's crust is one "reservoir" for measurements of abundance. A reservoir is any large body to be studied as unit, like the ocean, atmosphere, mantle or crust. Different reservoirs may have different relative amounts of each element due to different chemical or mechanical processes involved in the creation of the reservoir. [1]: 18
The vanadyl or oxovanadium(IV) cation, VO 2+, [1] is a functional group that is common in the coordination chemistry of vanadium. Complexes containing this functional group are characteristically blue and paramagnetic. A triple bond is proposed to exist between the V 4+ and O 2− centers. [2]
Warmer ocean water holds less oxygen and is more buoyant than cooler water. This leads to reduced mixing of oxygenated water near the surface with deeper water, which naturally contains less oxygen. Warmer water also raises oxygen demand from living organisms; as a result, less oxygen is available for marine life. [40]
Vanadium pentoxide is a commercially important catalyst for the production of sulfuric acid, a reaction that exploits the ability of vanadium oxides to undergo redox reactions. [2] The vanadium redox battery utilizes all four oxidation states: one electrode uses the +5/+4 couple and the other uses the +3/+2 couple. Conversion of these oxidation ...
In the water column of the ocean or deep lakes, vertical profiles of dissolved trace metals are characterized as following conservative–type, nutrient–type, or scavenged–type distributions. Across these three distributions, trace metals have different residence times and are used to varying extents by planktonic microorganisms.