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In a simple reaction such as the isomerization: there are two reactions to consider, the forward reaction in which the species A is converted into B and the backward reaction in which B is converted into A. If both reactions are elementary reactions, then the rate of reaction is given by [3]
The forward and reverse reactions are competing with each other and differ in reaction rates. These rates depend on the concentration and therefore change with the time of the reaction: the reverse rate gradually increases and becomes equal to the rate of the forward reaction, establishing the so-called chemical equilibrium.
In a chemical reaction, chemical equilibrium is the state in which both the reactants and products are present in concentrations which have no further tendency to change with time, so that there is no observable change in the properties of the system. [1] This state results when the forward reaction proceeds at the same rate as the reverse ...
In physical chemistry, the Arrhenius equation is a formula for the temperature dependence of reaction rates.The equation was proposed by Svante Arrhenius in 1889, based on the work of Dutch chemist Jacobus Henricus van 't Hoff who had noted in 1884 that the Van 't Hoff equation for the temperature dependence of equilibrium constants suggests such a formula for the rates of both forward and ...
The derivation from the reaction rate expressions is no longer considered to be valid. Nevertheless, Guldberg and Waage were on the right track when they suggested that the driving force for both forward and backward reactions is equal when the mixture is at equilibrium. The term they used for this force was chemical affinity.
Informally, the Kolmogorov forward equation addresses the following problem. We have information about the state x of the system at time t (namely a probability distribution p t ( x ) {\displaystyle p_{t}(x)} ); we want to know the probability distribution of the state at a later time s > t {\displaystyle s>t} .
A reversible reaction is a reaction in which the conversion of reactants to products and the conversion of products to reactants occur simultaneously. [1]+ + A and B can react to form C and D or, in the reverse reaction, C and D can react to form A and B.
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