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This page contains tables of azeotrope data for various binary and ternary mixtures of solvents. The data include the composition of a mixture by weight (in binary azeotropes, when only one fraction is given, it is the fraction of the second component), the boiling point (b.p.) of a component, the boiling point of a mixture, and the specific gravity of the mixture.
Aniline: 184.3 3.69 –5.96 ... Acetic Anhydride: 139.0 [6] Ethylene Dichloride: 1.25 83.5 −35 [7] ... Pyridine: 115.3 [24] Dimethylacetamide: 166.1
The Lumière–Barbier method is a method of acetylating aromatic amines in aqueous solutions. [1] Illustrative is the acetylation of aniline. First aniline is dissolved in water using one equivalent of hydrochloric acid. This solution is subsequently treated, sequentially, with acetic anhydride and aqueous sodium acetate. Aniline attacks ...
Acetic anhydride, or ethanoic anhydride, is the chemical compound with the formula (CH 3 CO) 2 O. Commonly abbreviated Ac 2 O , it is the simplest isolable anhydride of a carboxylic acid and is widely used as a reagent in organic synthesis .
Modern variations on the Dakin–West reaction permit many enolizable carboxylic acids – not merely amino acids – to be converted to their corresponding methyl ketones. For example, β-aryl carboxylic acids can be efficiently converted to β-aryl ketones by treatment of an acetic anhydride solution of the acid with catalytic N-methylimidazole.
Pyridine 0.982 Propanoic acid 0.993 Water 1.000 2-Methoxyethyl acetate 1.009 Benzonitrile 1.01 1-Methyl-2-pyrrolidinone 1.028 Hexamethylphosphoramide 1.03 1,4-Dioxane 1.033 Acetic acid 1.049 Acetic anhydride 1.08 Dimethyl sulfoxide 1.092 Chlorobenzene 1.1066 Deuterium oxide 1.107 Ethylene glycol 1.115 Diethylene glycol 1.118 Propylene carbonate
An example is zeotropic acetic acid and water. It is very difficult to separate out pure acetic acid (boiling point: 118.1 °C): progressive distillations produce drier solutions, but each further distillation becomes less effective at removing the remaining water. Distilling the solution to dry acetic acid is therefore economically impractical.
Aniline (from Portuguese anil 'indigo shrub', and -ine indicating a derived substance) [6] is an organic compound with the formula C 6 H 5 NH 2.Consisting of a phenyl group (−C 6 H 5) attached to an amino group (−NH 2), aniline is the simplest aromatic amine.