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Ammonium iron(II) sulfate, or Mohr's salt, is the inorganic compound with the formula (NH 4) 2 SO 4 ·Fe(SO 4)·6H 2 O.Containing two different cations, Fe 2+ and NH + 4, it is classified as a double salt of ferrous sulfate and ammonium sulfate.
As a salt of a strong acid (H 2 SO 4) and weak base (NH 3), its solution is acidic; the pH of 0.1 M solution is 5.5. In aqueous solution the reactions are those of NH + 4 and SO 2− 4 ions. For example, addition of barium chloride, precipitates out barium sulfate. The filtrate on evaporation yields ammonium chloride.
Atomic number Element Molar mass Formal standard atomic weight s.a.w., formal short Note Z calculated; g·mol −1 A r, standard [2] A r, abridged and conventional [2]; C 9 H 8 O 4: 180.159 g·mol −1
Copper(II) sulfate is an inorganic compound with the chemical formula Cu SO 4.It forms hydrates CuSO 4 ·nH 2 O, where n can range from 1 to 7. The pentahydrate (n = 5), a bright blue crystal, is the most commonly encountered hydrate of copper(II) sulfate, [10] while its anhydrous form is white. [11]
2 NH 3 + SO 2 + H 2 O → (NH 4) 2 SO 3. Ammonium sulfite is produced in gas scrubbers, now obsolete, consisting of ammonium hydroxide to remove sulfur dioxide from emissions from power plants. The conversion is the basis of the Walther Process. The resulting ammonium sulfite can be air oxidized to give ammonium sulfate. [4]
CuO + 2 HNO 3 → Cu(NO 3) 2 + H 2 O CuO + 2 HCl → CuCl 2 + H 2 O CuO + H 2 SO 4 → CuSO 4 + H 2 O. In presence of water it reacts with concentrated alkali to form the corresponding cuprate salts: 2 NaOH + CuO + H 2 O → Na 2 [Cu(OH) 4] It can also be reduced to copper metal using hydrogen, carbon monoxide, and carbon: CuO + H 2 → Cu + H ...
The latter is produced by the hydrogenation of nitric oxide using a platinum catalyst: [2] 2 NO + 3 H 2 + H 2 SO 4 → [NH 3 OH] 2 [SO 4] Another route to NH 2 OH is the Raschig process: aqueous ammonium nitrite is reduced by HSO − 3 and SO 2 at 0 °C to yield a hydroxylamido-N,N-disulfonate anion:: [3] [NH 4] + [NO 2] − + 2 SO 2 + NH 3 + H ...
Ammonium persulfate (APS) is the inorganic compound with the formula (NH 4) 2 S 2 O 8. It is a colourless (white) salt that is highly soluble in water, much more so than the related potassium salt. It is a strong oxidizing agent that is used as a catalyst in polymer chemistry, as an etchant, and as a cleaning and bleaching agent. [1]