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The main polycarbonate material is produced by the reaction of bisphenol A (BPA) and phosgene COCl 2. The overall reaction can be written as follows: The first step of the synthesis involves treatment of bisphenol A with sodium hydroxide, which deprotonates the hydroxyl groups of the bisphenol A. [6] (HOC 6 H 4) 2 CMe 2 + 2 NaOH → Na 2 (OC 6 ...
The type I reaction dominates, which cause chain scission at the carbonyl unit to give a range of products. [1] [38] Type II Norrish reactions are less common but give rise to acetaldehyde by way of vinyl alcohol esters. [36] This has an exceedingly low odour and taste threshold and can cause an off-taste in bottled water. [39]
Reagents are "substances or compounds that are added to a system in order to bring about a chemical reaction or are added to see if a reaction occurs." [1] Some reagents are just a single element. However, most processes require reagents made of chemical compounds. Some of the most common ones used widely for specific reactive functions are ...
The unique O=C bond is short (1.173 Å in the depicted example), while the C-O bonds are more ether-like (the bond distances of 1.326 Å for the example depicted). [1] Carbonate esters can be divided into three structural classes: acyclic, cyclic, and polymeric. The first and general case is the acyclic carbonate group.
For example, polyester chains grow by reaction of alcohol and carboxylic acid groups to form ester links with loss of water. However, there are exceptions; for example polyurethanes are step-growth polymers formed from isocyanate and alcohol bifunctional monomers) without loss of water or other volatile molecules, and are classified as addition ...
A polycarbonate is an oxocarbon dianion consisting of a chain of carbonate units, where successive carbonyl groups are directly linked to each other by shared additional oxygen atoms. That is, they are the conjugate bases of polycarbonic acids , the conceptual anhydrides of carbonic acid , or polymers of carbon dioxide .
One important class of condensation polymers are polyamides. [4] They arise from the reaction of carboxylic acid and an amine. Examples include nylons and proteins.When prepared from amino-carboxylic acids, e.g. amino acids, the stoichiometry of the polymerization includes co-formation of water:
Polycarbonate polyols are more expensive than other polyols and are thus used in more demanding applications. [31] [32] They have been used to make an isophorone diisocyanate based prepolymer which is then used in glass coatings. [33] They may be used in reactive hotmelt adhesives. [34] All polyols may be used to produce polyurethane prepolymers.