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Assuming initial atmospheric conditions (1 bar and 20 °C), the following table [1] lists the flame temperature for various fuels under constant pressure conditions. The temperatures mentioned here are for a stoichiometric fuel-oxidizer mixture (i.e. equivalence ratio φ = 1).
For many substances, the formation reaction may be considered as the sum of a number of simpler reactions, either real or fictitious. The enthalpy of reaction can then be analyzed by applying Hess' law, which states that the sum of the enthalpy changes for a number of individual reaction steps equals the enthalpy change of the overall reaction.
The heating value (or energy value or calorific value) of a substance, usually a fuel or food (see food energy), is the amount of heat released during the combustion of a specified amount of it.
A molecule is said to have a positive oxygen balance if it contains more oxygen than is needed and a negative oxygen balance if it contains less oxygen than is needed. [2] An explosive with a negative oxygen balance will lead to incomplete combustion, which commonly produces carbon monoxide, which is a toxic gas. Explosives with negative or ...
Theoretical oxygen demand (ThOD) is the calculated amount of oxygen required to oxidize a compound to its final oxidation products. [1] However, there are some differences between standard methods that can influence the results obtained: for example, some calculations assume that nitrogen released from organic compounds is generated as ammonia, whereas others allow for ammonia oxidation to ...
Equations should be balanced according to the stoichiometry, the number of atoms of each species should be the same on both sides of the equation. This is achieved by scaling the number of involved molecules (A, B, C and D in a schematic example below) by the appropriate integers a, b, c and d .
The standard Gibbs free energy of formation (G f °) of a compound is the change of Gibbs free energy that accompanies the formation of 1 mole of a substance in its standard state from its constituent elements in their standard states (the most stable form of the element at 1 bar of pressure and the specified temperature, usually 298.15 K or 25 °C).
This is illustrated in the image here, where the balanced equation is: CH 4 + 2 O 2 → CO 2 + 2 H 2 O. Here, one molecule of methane reacts with two molecules of oxygen gas to yield one molecule of carbon dioxide and two molecules of water. This particular chemical equation is an example of complete combustion. Stoichiometry measures these ...