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Pore structures in fresh concrete and air entrained in concrete. Concrete can be carbonated by two main methods: weathering carbonation and early age carbonation. [29] Weathering carbonation occurs in concrete when calcium compounds react with carbon dioxide (CO 2) from the atmosphere and water (H 2 O) in the concrete pores. The reaction is as ...
The carbon dioxide in the air reacts with the alkali in the cement and makes the pore water more acidic, thus lowering the pH. Carbon dioxide will start to carbonatate the cement in the concrete from the moment the object is made. This carbonatation process will start at the surface, then slowly moves deeper and deeper into the concrete.
A violet color indicates still alkaline areas and thus non-carbonated concrete. Carbonated zones favorable for steel corrosion and concrete degradation are colorless. [3] [4] The presence of water in carbonated concrete is necessary to lower the pH of concrete pore water around rebar and to depassivate the carbon steel surface at low pH.
In reinforced concrete, the chemical reaction between carbon dioxide In the air and calcium hydroxide and hydrated calcium silicate in the concrete is known as neutralisation. The similar reaction in which calcium hydroxide from cement reacts with carbon dioxide and forms insoluble calcium carbonate is carbonatation.
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As it depends on CO2 diffusion into the bulk of concrete, its rate depends on many parameters, such as environmental conditions and surface area exposed to the atmosphere. [73] [74] Carbonation is particularly significant at the latter stages of the concrete life - after demolition and crushing of the debris. It was estimated that during the ...
The initiation time is related to the rate at which carbonation propagates in the concrete cover thickness.Once that carbonation reaches the steel surface, altering the local pH value of the environment, the protective thin film of oxides on the steel surface becomes instable, and corrosion initiates involving an extended portion of the steel surface.
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