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This glossary of chemistry terms is a list of terms and definitions relevant to chemistry, including chemical laws, diagrams and formulae, laboratory tools, glassware, and equipment. Chemistry is a physical science concerned with the composition, structure, and properties of matter , as well as the changes it undergoes during chemical reactions ...
Chemistry is the scientific study of the properties and behavior of matter. [1] It is a physical science within the natural sciences that studies the chemical elements that make up matter and compounds made of atoms, molecules and ions: their composition, structure, properties, behavior and the changes they undergo during reactions with other substances.
The term is mainly used in coordination chemistry. The template effects emphasizes the pre-organization provided by the coordination sphere, although the coordination modifies the electronic properties (acidity, electrophilicity, etc.) of ligands. [1] An early example is the dialkylation of a nickel dithiolate: [2]
A good example from solid-state chemistry is the adducts of ethylene or carbon monoxide of CuAlCl 4. The latter is a solid with an extended lattice structure . Upon formation of the adduct, a new extended phase is formed in which the gas molecules are incorporated (inserted) as ligands of the copper atoms within the structure.
Examples include prolinol (from proline), valinol (from valine), tyrosinol (from tyrosine). Key members: ethanolamine , dimethylethanolamine , N -methylethanolamine , Aminomethyl propanol . Two popular drugs, often called alkanolamine beta blockers , are members of this structural class: propranolol , pindolol .
Physical chemistry, in contrast to chemical physics, is predominantly (but not always) a supra-molecular science, as the majority of the principles on which it was founded relate to the bulk rather than the molecular or atomic structure alone (for example, chemical equilibrium and colloids).
Cascade reactions are often key steps in the efficient total synthesis of complex natural products. The key step in Heathcock's synthesis of dihydroprotodaphniphylline features a highly efficient cascade involving two aldehyde/amine condensations, a Prins-like cyclization, and a 1,5-hydride transfer to afford a pentacyclic structure from an acyclic starting material.
In chemistry, metamerism is used to define the isomeric relationship between compounds with the same polyvalent, heteroatomic, functional group but differ in the main carbon chain or any of the side chains. It has rather been an obsolete term for isomerism, which has not been recognised by IUPAC in its publications. [1]