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The second law of thermodynamics is a physical law based on universal empirical observation concerning heat and energy interconversions.A simple statement of the law is that heat always flows spontaneously from hotter to colder regions of matter (or 'downhill' in terms of the temperature gradient).
By the principle of minimum energy, the second law can be restated by saying that for a fixed entropy, when the constraints on the system are relaxed, the internal energy assumes a minimum value. This will require that the system be connected to its surroundings, since otherwise the energy would remain constant.
According to the second law, in a reversible heat transfer, an element of heat transferred, , is the product of the temperature (), both of the system and of the sources or destination of the heat, with the increment of the system's conjugate variable, its entropy (): [1]
The principle of original horizontality states that layers of sediment are originally deposited horizontally under the action of gravity. [1] It is a relative dating technique. The principle is important to the analysis of folded and tilted strata. It was first proposed by the Danish geological pioneer Nicholas Steno (1638–1686).
The second law of thermodynamics is statistical in nature, and therefore its reliability arises from the huge number of particles present in macroscopic systems. It is not impossible, in principle, for all 6 × 10 23 atoms in a mole of a gas to spontaneously migrate to one half of a container; it is only fantastically unlikely—so unlikely ...
The principle of Uniformitarianism states that the geologic processes observed in operation that modify the Earth's crust at present have worked in much the same way over geologic time. [2] A fundamental principle of geology advanced by the 18th century Scottish physician and geologist James Hutton, is that "the present is the key to the past ...
The contact goniometer was the first instrument used to measure the interfacial angles of crystals. The International Union of Crystallography (IUCr) gives the following definition: "The law of the constancy of interfacial angles (or 'first law of crystallography') states that the angles between the crystal faces of a given species are constant, whatever the lateral extension of these faces ...
The principle of minimum energy is essentially a restatement of the second law of thermodynamics.It states that for a closed system, with constant external parameters and entropy, the internal energy will decrease and approach a minimum value at equilibrium.