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Nylon 66 (loosely written nylon 6-6, nylon 6/6, nylon 6,6, or nylon 6:6) is a type of polyamide or nylon. It, and nylon 6 , are the two most common for textile and plastic industries. Nylon 66 is made of two monomers each containing 6 carbon atoms, hexamethylenediamine and adipic acid , which give nylon 66 its name. [ 1 ]
Caprolactam molecule used to synthesize Nylon 6 by ring opening polymerization. Nylon 6 or polycaprolactam is a polymer, in particular semicrystalline polyamide.Unlike most other nylons, nylon 6 is not a condensation polymer, but instead is formed by ring-opening polymerization; this makes it a special case in the comparison between condensation and addition polymers.
One number after "PA" or "Nylon" indicates a homopolymer which is monadic or based on one amino acid (minus H 2 O) as monomer: PA 6 or Nylon 6: [NH−(CH 2) 5 −CO] n made from ε-caprolactam. Two numbers or sets of letters indicate a dyadic homopolymer formed from two monomers: one diamine and one dicarboxylic acid. The first number indicates ...
A step-growth copolymer -(-A-A-B-B-) n - formed by the condensation of two bifunctional monomers A–A and B–B is in principle a perfectly alternating copolymer of these two monomers, but is usually considered as a homopolymer of the dimeric repeat unit A-A-B-B. [6] An example is nylon 66 with repeat unit -OC-( CH 2) 4-CO-NH-(CH 2) 6-NH ...
The Zytel product line is based mostly on nylon 66, but also includes grades based on nylon 6 as a matrix, long chain nylons such as nylon 610 (if based on at least one renewable monomer they are branded Zytel RS), and copolymers including a transparent resin called Zytel 330.
[1] [2] Addition polymers can be formed by chain polymerization, when the polymer is formed by the sequential addition of monomer units to an active site in a chain reaction, or by polyaddition, when the polymer is formed by addition reactions between species of all degrees of polymerization. Addition polymers are formed by the addition of some ...
Almost all adiponitrile is hydrogenated to hexane-1,6-diamine for the production of nylon: [7] NC(CH 2) 4 CN + 4 H 2 → H 2 N(CH 2) 6 NH 2. Like other nitriles, adiponitrile is susceptible to hydrolysis; however, the resulting adipic acid is less expensively prepared via other routes.
Polymer nomenclature usually applies to idealized representations meaning minor structural irregularities are ignored. A polymer can be named in one of two ways. Source-based nomenclature can be used when the monomer can be identified. Alternatively, more explicit structure-based nomenclature can be used when the polymer structure is proven.