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The hydrophilic–lipophilic balance (HLB) of a surfactant is a measure of its degree of hydrophilicity or lipophilicity, determined by calculating percentages of molecular weights for the hydrophilic and lipophilic portions of the surfactant molecule, as described by Griffin in 1949 [1][2] and 1954. [3] Other methods have been suggested ...
Partition coefficient. In the physical sciences, a partition coefficient (P) or distribution coefficient (D) is the ratio of concentrations of a compound in a mixture of two immiscible solvents at equilibrium. This ratio is therefore a comparison of the solubilities of the solute in these two liquids. The partition coefficient generally refers ...
In 2008, Alpert coined the term, ERLIC [14] (electrostatic repulsion hydrophilic interaction chromatography), for HILIC separations where an ionic column surface chemistry is used to repel a common ionic polar group on an analyte or within a set of analytes, to facilitate separation by the remaining polar groups.
The n-octanol-water partition coefficient, Kow is a partition coefficient for the two-phase system consisting of n -octanol and water. [1] Kow is also frequently referred to by the symbol P, especially in the English literature. It is also called n-octanol-water partition ratio. [2][3][4] Kow serves as a measure of the relationship between lipophilicity (fat solubility) and hydrophilicity ...
The solution was initially prepared at 20 °C and then stored for 2 days at 4 °C. In chemistry, solubility is the ability of a substance, the solute, to form a solution with another substance, the solvent. Insolubility is the opposite property, the inability of the solute to form such a solution. The extent of the solubility of a substance in ...
Motivation & history First. Most of the hydrochemical software is designed for experts and scientists. In order to flatten the steep learning curve aqion provides an introduction to fundamental water-related topics in form of a "chemical pocket calculator".
Hydrophilic solids, which include many solids of biological origin, can readily absorb water. Polar interactions between water and the molecules of the solid favor partition of the water into the solid, which can allow significant absorption of water vapor even in relatively low humidity.
In computational chemistry, a water model is used to simulate and thermodynamically calculate water clusters, liquid water, and aqueous solutions with explicit solvent. The models are determined from quantum mechanics, molecular mechanics, experimental results, and these combinations. To imitate a specific nature of molecules, many types of ...